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US 12,503,374 B2Granted
Recycling of components contained in a residue obtained from the chloride process
AssigneeKronos International, Inc.
InventorsThomas Pierau, Frank Landwehr, Mitja Medved
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Abstract
The invention relates to a method for treating a residue obtained from the chloride process, wherein the residue comprises the components titanium dioxide, coke, an inert metal oxide, and an iron-containing component. Further, the invention refers to the use of this method to separate the components contained in said residue, and to the use of the separated components in the chloride process for obtaining titanium dioxide.
Claims18
A method for treating a residue obtained from the chloride process to obtain titanium dioxide, the method comprising:
- a) providing an aqueous suspension of the residue, wherein:
- the residue comprises titanium dioxide, coke, an inert metal oxide, and an iron containing component selected from the group consisting of iron (II) oxide, iron (III) oxide, iron (II) hydroxide, iron (III) hydroxide, iron (III) oxide hydroxide, and mixtures thereof;
- the iron-containing component is adhered to the surface of at least some of the titanium dioxide, coke, and/or the inert metal oxide in the form of shells thereby forming agglomerates;
- and
- the agglomerates remain present in the aqueous suspension;
- b) adjusting the pH of the aqueous suspension provided in step a) to a pH value of from about 3 to about 4;
- c) subjecting the aqueous suspension obtained in step b) to a step of deagglomerating the agglomerates of the residue to remove the iron-containing component from the surface of the titanium dioxide, coke, and/or the inert metal oxide and obtain the individual components of the residue,
- d) optionally, separating the coke from the aqueous suspension obtained in step c),
- e) separating the titanium dioxide from the aqueous suspension obtained in step c) or d), and
- f) optionally separating the iron-containing component from the aqueous suspension obtained in step c), d) or e).
7 more elements
Dependencies are inferred from the claim text.