Organic ammonium salts with traceability and detergent dispersant properties to liquid fuels and processes for their synthesis

A supramolecular surfactant of structural formula (14):

• wherein the surfactant comprises an AZO:A organic ammonium salt of structural formula (13):
• wherein:
• Ar:
• aromatic, such as an aryl, naphthol, naphthylamide, dimethylaniline, indole, pyrrole, pyrazolone, or substituted quinolones;
• R1:
• is a linear or branched alkyl or alkenyl chain ranging from C1 to C30 or a cycloalkyl or aryl group from C5 to C12 or aromatics, benzyls, naphthols, naphthylamines, or dimethyl anilines substituted with electron donors selected from NH2, OH, alkyl, and/or electro-attractors selected from the group consisting of COOR (ester), CO (ketone), COOH, CN, NO2, and SO3H;
• R2:
• is a substituent of a protic and/or acidic nature selected from the group COOH, SO3H, and OH;
• R3:
• is H or a linear or branched alkyl or alkenyl chain from C1 to C32, or a cycloalkyl or aryl group from C5 to C12, or aromatics, benzyls, naphthols, naphthylamines, or substituted dimethyl anilines;
• R4:
• is H, or a linear or branched alkyl or alkenyl chain from C1 to C32, or a cycloalkyl or aryl group from C5 to C12 or aromatics, benzyls, naphthols, naphthylamines or substituted dimethyl anilines;
• and
• R5:
• a linear or branched alkyl or alkenyl chain from C1 to C32, or a cycloalkyl or aryl group from C5 to C12, or primary, secondary or tertiary amino alcohols, linear or branched, cyclic or aromatics and/or derived from poly-isobutenyl-succinic anhydrides, poly-isobutylene, poly-isobutenylphenols or Mannich bases,
• non-covalently interacting with an organic compound OC of structural formula (6),
• wherein:
• R6:
• is hydrogen, or a linear or branched alkyl or alkenyl chain ranging from C1 to C32, or a cycloalkyl or aryl group from C5 to C12, or substituted aromatic and/or derived from poly-isobutenyl-succinic anhydrides, poly-isobutylene, poly-isobutenylphenols or Mannich bases;
• R7:
• is a linear or branched alkyl or alkenyl chain ranging from C1 to C32, or a cycloalkyl or aryl group from C5 to C12, or substituted aromatic;
• R8:
• is hydrogen, or a linear or branched alkyl or alkenyl chain ranging from C1 to C32, or a cycloalkyl or aryl group from C5 to C12, or substituted aromatic with —OH and —NH2 groups;
• n:
• it has values between zero and four;
• D1:
• nitrogen with substituents R6 and R7;
• and
• D2:
• is selected from oxygen, nitrogen, or sulfur as a substituent of the R8 group.