Back to results
US 12,404,359 B2Granted
Rubber polymer, method for preparing thereof, and rubber composition comprising the same
AssigneeKorea Kumho Petrochemical Co., Ltd.
InventorsHan Baek Lee, Hoo-Chae Kim, Seung-Hwon Lee, Seung Hyun Do, Daejune Joe
Life of this patent
Estimating the term…
Abstract
Disclosed are a rubber polymer including a unit structure derived from a conjugated diene-based monomer and at least one of compounds represented by Chemical Formula 1 to Chemical Formula 4, a method of preparing the same, and a rubber composition including the same.
Claims9
A rubber polymer comprising a unit structure derived from a conjugated diene-based monomer and at least one of compounds represented by the following Chemical Formula 4:
- in Chemical Formulas,
- B is oxygen or sulfur,
- C is silicon or tin,
- Z is a functional group represented by the following Chemical Formula Z,
- each R2 is independently a C1 to C20 linear or branched substituted or unsubstituted alkyl group, a C3 to C20 substituted or unsubstituted cycloalkyl group, or a C6 to C20 substituted or unsubstituted aryl group,
- wherein:
- the rubber polymer is prepared by using a polymerization system including a neodymium-based catalyst,
- the rubber polymer has a degree of branching of 2.0 to 2.5,
- the rubber polymer has a molecular weight distribution (Mw/Mn) of 1.5 to 2.5, and
- the degree of branching is calculated by the ratio of the Mooney viscosity (MV) and solution viscosity (SV) at 25° C., multiplied by 10(MV/SV*10).
7 more elements
A method of preparing a rubber polymer, comprising the steps of:
- (a) allowing a conjugated diene-based monomer to react in the presence of a catalyst;
- and
- (b) allowing the product of the step (a) to react with at least one of compounds represented by the following Chemical Formula 4:
- in Chemical Formula,
- B is oxygen or sulfur,
- C is silicon or tin,
- Z is a functional group represented by the following Chemical Formula Z,
- each R2 is independently a C1 to C20 linear or branched substituted or unsubstituted alkyl group, a C3 to C20 substituted or unsubstituted cycloalkyl group, or a C6 to C20 substituted or unsubstituted aryl group,
- wherein:
- the rubber polymer is prepared by using a polymerization system including a neodymium-based catalyst,
- the rubber polymer has a degree of branching of 2.0 to 2.5,
- the rubber polymer has a molecular weight distribution (Mw/Mn) of 1.5 to 2.5, and
- the degree of branching is calculated by the ratio of the Mooney viscosity (MV) and solution viscosity (SV) at 25° C., multiplied by 10(MV/SV*10).
10 more elements
Dependencies are inferred from the claim text.