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US 12,351,677 B2Granted
Liquid epoxy resin composition useful for making polymers
AssigneeSwimc LLC
InventorsRichard H. Evans, Benjamin J. Webster, Robert M. O'Brien, Jeffrey Niederst
Life of this patent
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Abstract
A liquid epoxy resin composition is provided. In preferred embodiments, the liquid epoxy resin composition is free of bisphenol A, bisphenol F, and bisphenol S, including epoxides thereof, and is useful in preparing a polyether polymer having utility in coating compositions, including, e.g., coating compositions for use on food or beverage containers.
Claims23
A method of making an aromatic polyether polymer comprising:
- providing a liquid epoxy resin composition that is prepared by reacting reactants including one or more epihalohydrins and one or more ortho-substituted diphenol compounds, wherein the liquid epoxy resin composition comprises diepoxide resins, optional mono-epoxide compounds, and optional unreacted ortho-substituted diphenol compounds;
- each optional mono-epoxide compound comprising a base structural unit derived from an ortho-substituted diphenol compound of said one or more ortho-substituted diphenol compounds;
- each diepoxide resin comprising a base structural unit derived from an ortho-substituted diphenol compound of said one or more ortho-substituted diphenol compounds and an “n” number of additional structural units derived from said ortho-substituted diphenol compound;
- and wherein the liquid epoxy resin composition comprises more than 60 and less than 80 weight percent of n=0 diepoxide resins, based on the total weight of said diepoxide resins, any mono-epoxide compounds, and any unreacted ortho-substituted diphenol compounds;
- and wherein the liquid epoxy resin composition is a liquid at 20° C. and atmospheric pressure;
- and
- reacting the liquid epoxy resin composition with one or more extender compounds to yield an aromatic polyether polymer having a number average molecular weight of at least 2,000;
- wherein the aromatic polyether polymer is substantially free of bisphenol A, epoxides of bisphenol A, bisphenol F, epoxides of bisphenol F, bisphenol S, and epoxides of bisphenol S.
5 more elements
Dependencies are inferred from the claim text.