Solid oxide and chemically-treated solid oxide catalysts for the pyrolysis of polyethylene
AssigneeChevron Phillips Chemical Company LP
InventorsDavid W. Dockter, Max P. McDaniel, Kathy S. Clear
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Abstract
Pyrolysis processes comprise contacting a waste polyolefin with a solid catalyst at a pyrolysis temperature to form a pyrolysis product containing C1-C10 hydrocarbons. In some instances, the solid catalyst can be a silica-coated alumina, a fluorided silica-coated alumina, or a sulfated alumina, while in other instances, the solid catalyst can be any suitable solid oxide or chemically-treated solid oxide that is characterized by a d50 average particle size from 5 to 12 μm and a particle size span from 0.7 to 1.7. Hydrocarbon compositions are formed from the pyrolysis of waste polyolefins with specific amounts of methane and higher carbon number hydrocarbons.
Claims20
A catalyst comprising a sulfated solid oxide, the catalyst characterized by:
- a d50 average particle size in a range from 5 to 12 μm;
- and
- a particle size span ((d90−d10)/d50) in a range from 0.7 to 1.7.
Dependencies are inferred from the claim text.