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US 12,215,181 B2Granted
Anionic group III complexes as weakly coordinating anions for olefin polymerization catalyst activators
AssigneeDow Global Technologies LLC
InventorsTodd D. Senecal, Sukrit Mukhopadhyay, Richard J. Keaton, Jerzy Klosin, Rafael Huacuja, David M. Pearson, William H. H. Woodward
Life of this patent
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Abstract
Embodiments include activators having a structure according to formula (I).
Claims11
An activator having a structure according to formula (I):
- where:
- M is a metal in a +3 oxidation state, the metal being selected from boron, aluminum, gallium, scandium, yttrium, or a lanthanide;
- [Cat]+ is +N(H)RN3, wherein each RN is independently (C1-C20) alkyl;
- or +C(C6H4RC)3, wherein each RC is independently chosen from (C1-C30) alkyl;
- or [HN(RS)(RN)2]+, where RN is (C1-C20) alkyl and RS is chosen from (C1-C30) alkyl, (C6-C20) aryl, (C5-C20) heteroaryl, or —H;
- R1, R2, R3, R4 R5, R6, R7, R8, R9, R10, R11, R12, R13, R14, R15, and R16 are independently chosen from (C1-C40) alkyl, (C6-C40) aryl, —H, —NRC2, —ORC, —SRC, or halogen, wherein each RC is independently a (C1-C30) hydrocarbyl or —H, provided at least one of R1-4, and one of R5-8, and one of R9-12, and one of R13-16 is a fluorine-substituted (C1-C40) alkyl, a fluorine-substituted (C6-C40) aryl, or —F;
- and
- R17 and R18 are (C1-C40) alkyl, (C1-C40) heteroalkyl, a fluorine-substituted (C1-C40) alkyl, or a fluorine-substituted (C6-C40) aryl.
5 more elements
Dependencies are inferred from the claim text.