Processes for producing a shaped body using polyamide blends containing a polyarylether
AssigneeBASF SE
InventorsClaus Gabriel, Martin Weber, Philipp Kloke, Thomas Meier
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Abstract
The present invention relates to a process for producing a shaped body by selective laser sintering of a sinter powder (SP). The sinter powder (SP) comprises at least one semicrystalline polyamide, at least one nylon-6I/6T and at least one polyaryl ether. The present invention further relates to a shaped body obtainable by the process of the invention and to the use of a polyaryl ether in a sinter powder (SP) for broadening the sintering window (WSP) of the sinter powder (SP).
Claims10
A process for producing a shaped body by selective laser sintering of a sinter powder (SP), wherein the sinter powder (SP) comprises the following components:
- (A) at least one semicrystalline polyamide comprising at least one unit selected from the group consisting of —NH—(CH2)m—NH— units where m is 4, 5, 6, 7 or 8, —CO—(CH2)n—NH— units where n is 3, 4, 5, 6 or 7, and —CO—(CH2)o—CO— units where o is 2, 3, 4, 5 or 6,
- (B) at least one nylon-6I/6T,
- (C) at least one polyaryl ether,
- wherein
- component (C) is a polyaryl ether containing units of the general formula (I)
- with the following definitions:
- t, q:
- each independently 0, 1, 2 or 3,
- Q, T, Y:
- each independently a chemical bond or group selected from —O—, —S—, —SO2—, S═O, C═O, —N═N— and —CRaRb— where Ra and Rb are each independently a hydrogen atom or a C1-C12-alkyl, C1-C12-alkoxy or C6-C18-aryl group and where at least one of Q, T and Y is-SO2— and
- Ar, Ar1:
- each independently an arylene group having from 6 to 18 carbon atoms, and wherein a first layer of the sinter powder (SP) is arranged in a powder bed and locally exposed to a laser beam, and wherein the sinter powder (SP) comprises in the range from 20% to 90% by weight of component (A), in the range from 5% to 40% by weight of component (B) and in the range from 5% to 40% by weight of component (C), based in each case on the sum total of the percentages by weight of components (A), (B) and (C).
A process for broadening the sintering window (WSP) of a sinter powder (SP) compared to the sintering window (WAB) of a mixture of components (A) and (B) which comprises incorporating into the sinter powder at least one polyaryl ether in the sinter powder (SP) comprising the following components:
- (A) at least one semicrystalline polyamide comprising at least one unit selected from the group consisting of —NH—(CH2)m—NH— units where m is 4, 5, 6, 7 or 8, —CO—(CH2)n—NH— units where n is 3, 4, 5, 6 or 7, and —CO—(CH2)o—CO— units where o is 2, 3, 4, 5 or 6,
- (B) at least one nylon-6I/6T,
- (C) at least one polyaryl ether,
- where the sintering window (WSP;
- WAB) in each case is the difference between the onset temperature of melting (TMonset) and the onset temperature of crystallization (TConset), wherein
- the polyaryl ether contains units of the general formula (I)
- with the following definitions:
- t, q:
- each independently 0, 1, 2 or 3,
- Q, T, Y:
- each independently a chemical bond or group selected from —O—, —S—, —SO2—, S═O, C═O, —N═N— and —CRaRb— where Ra and Rb are each independently a hydrogen atom or a C1-C12-alkyl, C1-C12-alkoxy or C6-C18-aryl group and where at least one of Q, T and Y is-SO2— and
- Ar, Ar1:
- each independently an arylene group having from 6 to 18 carbon atoms, wherein the sinter powder (SP) comprises in the range from 20% to 90% by weight of component (A), in the range from 5% to 40% by weight of component (B) and in the range from 5% to 40% by weight of component (C), based in each case on the sum total of the percentages by weight of components (A), (B) and (C).
Dependencies are inferred from the claim text.