Poly (phenylene ether) based compatibilizing material
AssigneeShpp Global Technologies B.V.
InventorsEylem Tarkin-Tas, Huseyin Tas, Nikhil Verghese
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Abstract
Compatibilizing materials for use with fibers and polymeric compositions are described. A compatibilizing material can include a silane (Si) modified polyphenylene ether (PPE) oligomer having a resin reactive functional group. The resin reactive functional group can be between the PPE moiety and a Si moiety. In other instances, the resin reactive functional group can be a substituent of the Si moiety.
Claims16
A compatibilizing material comprising a silane (Si) modified polyphenylene ether (PPE) oligomer having a resin reactive functional group, wherein the resin reactive functional group is (1) a substituent of the PPE oligomer, (2) positioned between the PPE portion of the oligomer and the Si portion of the oligomer, (3) a substituent of the Si portion of the oligomer, or (4) a combination thereof;
- wherein the compatibilizing material has the structure:
- wherein A is the polyphenylene ether oligomer, a is 0 to 12, b is 0 to 12, R1 is a resin reactive group, R2 is a hydrogen (H), a substituted or unsubstituted hydrocarbyl group, R3 is a H, a substituted or unsubstituted hydrocarbyl group, or a substituted or unsubstituted alkoxy group, and R4 is a H, a substituted hydrocarbyl group, an unsubstituted hydrocarbyl group, a substituted aromatic group or an unsubstituted aromatic group;
- or R4 has the structure of:
- wherein c is 0 to 12;
- d is 0 to 12;
- R5 is a resin reactive group;
- R6 is a H, a substituted or unsubstituted hydrocarbyl group;
- and R7 is a H, a substituted or unsubstituted hydrocarbyl group, or a substituted or unsubstituted alkoxy group;
- or
- wherein the compatibilizing material has the structure:
- wherein A is the polyphenylene ether oligomer, Y is a linking group comprising a resin reactive functional group R10;
- R2 is a H, a substituted or unsubstituted hydrocarbyl group;
- R3 and R8 are each independently a H, a substituted or unsubstituted hydrocarbyl group, or a substituted or unsubstituted alkoxy group;
- and R9 is a H, a substituted hydrocarbyl group or an unsubstituted hydrocarbyl group;
- wherein the resin reactive group comprises an epoxy group, a substituted epoxy group, an olefin-containing group, a substituted olefin-containing group, an acrylate group, a substituted acrylate group, a cyano group, a substituted cyano group, a hydroxy group, or any combination thereof.
A compatibilizing material, having the structure of
- where, and R2 is H, a substituted or unsubstituted hydrocarbyl group, R3 is a H, a substituted or unsubstituted hydrocarbyl group, or a substituted or unsubstituted alkoxy group, a is 0 to 12, b is 0 to 12, and z is 2 to 30;
- where k is 1 to 10, z is 1 to 40, R2 is H, a substituted or unsubstituted hydrocarbyl group, and R3 and R8 each independently is a H, a substituted or unsubstituted hydrocarbyl group, or a substituted or unsubstituted alkoxy group;
- or
- where R22 and R23 each independently is a hydrocarbyl or substituted hydrocarbyl group, R is an epoxy group, a substituted epoxy group, an olefin-containing group, a substituted olefin-containing group, an acrylate group, a substituted acrylate group, a cyano group, a substituted cyano group, a cyanate group a hydroxy group, or any combination thereof, i is 0 to 6 and j is 0 to 6, and z is 1 to 30.
Dependencies are inferred from the claim text.