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US 12,179,174 B2Granted
Method for preparing an iron oxide particle core composite
AssigneeKing Fahd University of Petroleum and Minerals
InventorsTawfik Abdo Saleh Awadh, Akram Abdulhakeem Al-Absi
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Abstract
A polymer/activated carbon composite made up of a branched polyethylenimine and magnetic cores involving Fe3O4 disposed activated carbon. The magnetic cores have activated carbonyl groups on the surface. A process for removing organic dyes, such as methyl red, as well as heavy metal ions from a polluted aqueous solution or an industrial wastewater utilizing the composite is introduced. A method of synthesizing the polymer/activated carbon composites is also specified.
Claims12
A method of preparing a composite, comprising:
- treating an activated carbon with an acid to form a carboxylated carbon, wherein the acid is selected from the group consisting of HNO3, H2SO4, H3PO4 and HClO4;
- mixing the carboxylated carbon, a Fe(II) salt, a Fe(III) salt, and a base in the presence of a solvent to form a mixture;
- heating the mixture to form a magnetic carbon;
- mixing the magnetic carbon and a halide reagent to form a magnetic core;
- and
- reacting the magnetic core with a branched polyethylenimine thereby forming the composite,
- wherein the halide reagent is at least one selected from the group consisting of a thionyl halide, an oxalyl halide, phosphorus trihalide, and phosphorous pentahalide,
- wherein the magnetic core comprises Fe3O4 disposed on the activated carbon and the branched polyethylenimine,
- wherein the Fe3O4 is in the form of nanoparticles having an average particle size of 1-100 nm;
- and
- wherein the magnetic core comprises acyl halide groups on a surface of the magnetic core.
8 more elements
Dependencies are inferred from the claim text.