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US 12,015,142 B2Granted
Methods involving use of nitrogen-containing plasma to treat liquid electrolyte lithium-ion cathode materials
OwnerVenkatraman Prabhakarinventor
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Abstract
Systems and methods related to manufacturing of Lithium-Ion cells and Lithium-Ion cell cathode materials are disclosed. In one exemplary implementation, there is provided a method of using a Nitrogen-containing plasma to treat the Lithium-Ion cell cathode materials. Moreover, the method may include treating the cathode materials before and/or after coating the cathode materials on a metal foil.
Claims27
A method of fabricating a Lithium-ion cell, the method comprising:
- coating a cathode powder on a metal foil to produce a cathode-coated metal foil;
- wherein the cathode powder comprises one or more cathode active materials;
- wherein the cathode powder contains Lithium, Nickel, and Oxygen and the one or more cathode active materials have a chemical formula of Li(NixMnyCozAlw)O2, wherein 0.6≤x≤0.95, 0.02≤y≤0.2, 0≤z≤0.2, 0≤w≤0.1, and the Lithium is not lithium excess;
- drying, by one or more dryer chambers, the cathode-coated metal foil, wherein each of the one or more dryer chambers is configured with a header, a solvent exhaust collection and a recovery system;
- exposing, by at least one plasma chamber, the cathode-coated metal foil with treating material comprising nitrogen containing plasma having a nitrogen-containing reactive gas that reacts with the one or more cathode active materials to incorporate Nitrogen into the Lithium-ion cell's cathode, wherein the plasma is a near-atmospheric pressure plasma source ranging from about 0.5 to about 1.5 atmospheres pressure;
- calendering or rolling the cathode-coated metal foil treated to incorporate the Nitrogen;
- and
- placing the cathode-coated foil, treated to incorporate the Nitrogen, in a receptacle with a liquid electrolyte, to yield the Lithium-ion cell.
5 more elements
Dependencies are inferred from the claim text.