Method of producing negative electrode
AssigneeLG Energy Solution, Ltd.
InventorsOh Byong Chae, Ye Ri Kim
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Abstract
A method of producing a negative electrode is disclosed which is capable of preventing volume expansion and structural deformation caused by pre-lithiation, maintaining proximity and contact between negative electrode active materials, preventing an increase in resistance of a negative electrode, and realizing an excellent capacity retention rate by performing pre-lithiation while pressurizing a negative electrode at a specific pressure. In addition, the method of producing a negative electrode is capable of improving quality consistency of a product and processability by performing pre-lithiation of a negative electrode in a roll-to-roll manner.
Claims14
A method of producing a negative electrode, comprising:
- providing a negative electrode roll on which a negative electrode structure including a negative electrode current collector and a negative electrode active material layer formed on at least one surface of the negative electrode current collector is wound;
- providing a pre-lithiation bath containing a pre-lithiation solution, the pre-lithiation bath being sequentially divided into an impregnation section and a pre-lithiation section;
- impregnating the negative electrode structure with the pre-lithiation solution while unwinding the negative electrode structure from the negative electrode roll and moving the negative electrode structure through the impregnation section;
- and
- pre-lithiating the impregnated negative electrode structure by disposing the impregnated negative electrode structure in the pre-lithiation section,
- wherein the pre-lithiating the impregnated negative electrode structure includes:
- (a) disposing the impregnated negative electrode structure between two pre-lithiation structures, each pre-lithiation structure including a separator layer disposed to face the negative electrode active material layer and a lithium counter electrode layer located on the separator layer;
- (b) electrochemical charging the impregnated negative electrode structure while pressurizing the impregnated negative electrode structure at a pressure of 10 kPa to 3,500 kPa with the two pre-lithiation structures to form a pre-lithiated negative electrode structure;
- and
- (c) separating the two pre-lithiation structures from the pre-lithiated negative electrode structure and moving the pre-lithiated negative electrode structure out of the pre-lithiation section.
Dependencies are inferred from the claim text.