Caustic conversion process
AssigneesAustralian Nuclear Science and Technology Organisation, Lithium Australia Limited
InventorsAndrew Napier, Christopher Griffith
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Abstract
The disclosure relates to processes for extracting lithium from an uncalcined lithium-bearing silicate and recovering a lithium salt therefrom. A slurry of the uncalcined lithium-bearing silicate and a caustic solution is heated in an autoclave to provide a Li-rich sodalite phase. The Li-rich sodalite phase is leached with a dilute acid to produce a lithium-rich pregnant liquor. Various subsequent processes to treat the lithium-rich pregnant liquor to recover a lithium salt, such as lithium phosphate, lithium carbonate, lithium sulphate or lithium hydroxide, are described.
Claims19
A process for extracting lithium from an uncalcined lithium-bearing silicate comprising:
- a) heating a slurry of the uncalcined lithium-bearing silicate and a caustic solution in an autoclave to produce a Li-rich sodalite phase;
- and
- b) leaching the Li-rich sodalite phase with a dilute acid having a pH of 2-6 to produce a lithium-rich pregnant liquor.
Dependencies are inferred from the claim text.