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US 11,999,762 B2Granted
Phosphine precursor for preparing quantum dot and quantum dot prepared therefrom
AssigneeSK Chemicals Co., Ltd.
InventorsJeong Ho Park, Hee Il Chae, Kyung Sil Yoon, Ju-Sik Kang, Yu Mi Chang, Nam-Choul Yang, Jae Kyun Park, Song Lee
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Abstract
The present invention relates to a phosphine precursor for the preparation of a quantum dot, and a quantum dot prepared therefrom. Using the phosphine precursor for the preparation of a quantum dot of the present invention, a quantum dot with improved luminous efficiency and higher luminous color purity can be provided.
Claims6
A method for preparing a phosphine precursor represented by the following Chemical Formula 1, comprising the steps of:
- preparing a mixture of (i) a primary phosphine compound having the formula Q1PH2 or a secondary phosphine compound having the formula Q1Q2PH, (ii) an ether solvent, and (iii) alkyl lithium;
- and
- adding a silyl halide compound to the mixture:
- in the Chemical Formula 1,
- Q1 is
- Q2 iS
- Q3 is
- wherein R1 to R9 are identical to or different from each other, and each independently, C1-20 linear or branched alkyl, C6-30 aryl, C7-30 alkylaryl, or C7-30 arylalkyl, and
- wherein at least one pair selected from the group consisting of (i) Q1 and Q2, (ii) Q1 and Q3, and (iii) Q2 and Q3 are different from each other.
6 more elements
Dependencies are inferred from the claim text.