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US 11,965,694 B2Granted
Process and apparatus for the cryogenic separation of a mixture of carbon monoxide, hydrogen and methane for the production of CH4
AssigneeL'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
InventorsManon Cortale, Bertrand Demolliens, Antoine Hernandez, Guillaume Teixeira
Life of this patent
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Abstract
In a process of the separation of a mixture of carbon monoxide, hydrogen and methane, the mixture is sent to a scrubbing column, a bottom liquid withdrawn at the bottom of the scrubbing column is depleted in hydrogen with respect to the mixture and is sent to a stripping column, a bottom liquid from the stripping column is sent to a separation column and a liquid enriched in methane withdrawn from the bottom of the separation column is vaporized in order to form a final product.
Claims15
A process for separation of a mixture comprising carbon monoxide, hydrogen and methane, the process comprising the steps of:
- i) sending the mixture or a fluid derived from the mixture, after cooling to a cryogenic temperature in a heat exchanger, to a scrubbing column fed at a top portion with a liquid containing at least 80 mol % carbon monoxide or to at least one phase separator;
- ii) withdrawing a bottom liquid at a bottom portion of the scrubbing column or of the phase separator or of one of the phase separators that is depleted in hydrogen with respect to the mixture and then sending the bottom liquid to a stripping column;
- iii) withdrawing a gas at a top portion of the stripping column;
- iv) sending a bottom liquid from the stripping column to a separation column that is configured to separate the bottom liquid into a top gas enriched in carbon monoxide and a liquid enriched in methane;
- and
- v) withdrawing the liquid enriched in methane from a bottom portion of the separation column and then vaporizing the liquid enriched in methane in the heat exchanger in order to form gaseous methane,
- wherein the gaseous methane is compressed in a compressor and a first part of the gaseous methane following compression is returned at the bottom of the separation column for separation therein, and a second part of the gaseous methane following compression is collected as a compressed methane product stream,
- wherein the separation column has a top condenser cooled by a closed nitrogen cycle comprising a gaseous nitrogen compressor or by a closed carbon monoxide cycle comprising a gaseous carbon monoxide compressor,
- wherein the first part of the gaseous methane following compression that is returned to the bottom of the separation column has the same methane concentration as the liquid enriched in methane withdrawn the bottom portion of the separation column.
6 more elements
An apparatus for separation of a mixture comprising carbon monoxide, hydrogen and methane, the apparatus comprising:
- a scrubbing column having a top portion and/or at least one phase separator;
- a stripping column having a top portion and a bottom portion;
- a separation column having a top portion and a bottom portion;
- a heat exchanger;
- means for sending the mixture to be cooled to a cryogenic temperature to the heat exchanger;
- means for sending the cooled mixture or a fluid derived from said cooled mixture to the scrubbing column fed at the top portion with a liquid containing at least 80 mol % carbon monoxide and/or to at least one phase separator;
- means for withdrawing a bottom liquid from the scrubbing column and/or the at least one phase separator, wherein the bottom liquid is depleted in hydrogen with respect to the mixture;
- means for sending the withdrawn bottom liquid to the stripping column;
- means for withdrawing a gas at the top portion of the stripping column;
- means for sending a bottom liquid from the stripping column to the separation column, wherein the separation column is configured to separate the bottom liquid into a top gas enriched in carbon monoxide and a liquid enriched in methane;
- means for withdrawing the liquid enriched in methane from the bottom of the separation column, wherein the means for withdrawing the liquid enriched in methane are in fluid communication with the heat exchanger in order to form gaseous methane;
- a compressor;
- means for sending the gaseous methane to the compressor;
- and
- means for returning a part of the gaseous methane following compression in the compressor to the bottom portion of the separation column for separation therein,
- wherein the separation column comprises a top condenser that is cooled by a closed refrigeration cycle, wherein the closed refrigeration cycle is selected from the group consisting of a closed nitrogen refrigeration cycle and a closed carbon monoxide refrigeration cycle,
- wherein the part of the gaseous methane following compression that is returned to the bottom of the separation column has the same methane concentration as the liquid enriched in methane withdrawn the bottom portion of the separation column.
14 more elements
Dependencies are inferred from the claim text.