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US 11,909,037 B2Granted
Positive electrode and lithium battery including the same
AssigneesSamsung Electronics Co., Ltd., Samsung SDI Co., Ltd.
InventorsHongsoo Choi, Hyeokjo Gwon, Soyeon Kim, Hyunseok Kim, Wonseok Chang
Life of this patent
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Abstract
A positive electrode includes a composite material including a positive active material and a coating layer on a surface of the positive active material, wherein the coating layer includes a copolymer including a first repeating unit represented by Formula 1 below and a second repeating unit represented by Formula 2 below: wherein Ar1, R1 to R6, A, A1, Y−, m, and n are the same as defined in the specification.
Claims19
A positive electrode for a lithium battery comprising:
- a composite material comprising
- a positive active material as a core of the composite material, and
- a coating layer located on a surface of the positive active material forming a shell on the core of the composite material,
- wherein the coating layer comprises a copolymer comprising a first repeating unit represented by Formula 1, and a second repeating unit represented by Formula 2:
- wherein in Formula 1,
- Ar1 is a substituted or unsubstituted C6-C30 arylene group or a substituted or unsubstituted C6-C30 heteroarylene group,
- R1, R2, and R3 are each independently hydrogen, a substituted or unsubstituted C1-C30 alkyl group, a substituted or unsubstituted C6-C30 aryl group, or a substituted or unsubstituted C3-C30 heteroaryl group,
- A is a bond, a substituted or unsubstituted C1-C30 alkylene group, a substituted or unsubstituted C6-C30 arylene group, a substituted or unsubstituted C3-C30 heteroarylene group, a substituted or unsubstituted C4-C30 cycloalkylene group, or a substituted or unsubstituted C3-C30 heterocycloalkylene group,
- is a 3-membered to 31-membered ring system comprising 2 to 30 carbon atoms, and X is —S, —N(R), or —P(R′),
- R and R′ are each independently hydrogen, a substituted or unsubstituted C1-C30 alkyl group, a substituted or unsubstituted C1-C30 heteroalkyl group, a substituted or unsubstituted C1-C30 alkoxy group, a substituted or unsubstituted C6-C30 aryl group, a substituted or unsubstituted C7-C30 arylalkyl group, a substituted or unsubstituted C6-C30 aryloxy group, a substituted or unsubstituted C3-C30 heteroaryl group, a substituted or unsubstituted C4-C30 heteroarylalkyl group, a substituted or unsubstituted C3-C30 cycloalkyl group, a substituted or unsubstituted C2-C30 alkenyl group, or a substituted or unsubstituted C3-C30 alkynyl group, and
- Y− is an anion,
- wherein in Formula 2,
- A1 is —C(═O)O—(CH2CH2O)a—R7, wherein R7 is hydrogen, a substituted or unsubstituted C1-C30 alkyl group, or a substituted or unsubstituted C6-C30 aryl group, and a is an integer of 1 to 10, and
- R4, R5, and R6 are each independently hydrogen, a substituted or unsubstituted C1-C30 alkyl group, a substituted or unsubstituted C6-C30 aryl group, or a substituted or unsubstituted C3-C30 heteroaryl group, and
- in Formulae 1 and 2, m and n are mole fractions of the first repeating unit represented by Formula 1 and the second repeating unit represented by Formula 2, respectively, wherein a sum of m and n is 1, and m and n are each independently greater than 0 and less than 1.
12 more elements
Dependencies are inferred from the claim text.