Multi-stage process for producing a C2 to C8 olefin polymer composition
AssigneeBorealis AG
InventorsKlaus Nyfors, Vasileios Kanellopoulos, Erno Elovainio, Ravindra Tupe, Victor Sumerin
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Abstract
The present invention relates to a multi-stage process for producing a C2 to C8 olefin polymer composition in a process comprising at least two reactors, wherein a pre-polymerized solid Ziegler-Natta catalyst is prepared by carrying out an off-line pre-polymerization of a solid Ziegler-Natta catalyst component with a C2 to C4 olefin monomer before feeding to the polymerization process.
Claims15
A continuous multi-stage process for producing a C2 to C8 olefin polymer composition in at least two reactors, the continuous multi-stage process comprising the steps of:
- a) introducing a stream of a pre-polymerized solid Ziegler-Natta catalyst and a monomer of C2 to C8 olefin into a first polymerization reactor, thereby producing in a first polymerization a first C2 to C8 olefin polymer;
- b) withdrawing a stream comprising the first C2 to C8 olefin polymer from the first polymerization reactor and passing it into a second polymerization reactor;
- c) introducing a stream of a monomer of C2 to C8 olefin into the second polymerization reactor, thereby producing in a second polymerization a first polymer mixture comprising the first C2 to C8 olefin polymer and a second C2 to C8 olefin polymer produced in the second polymerization reactor;
- and
- d) withdrawing a stream comprising the first polymer mixture from the second polymerization reactor, thereby obtaining the C2 to C8 olefin polymer composition;
- wherein the pre-polymerized solid Ziegler-Natta catalyst is prepared by off-line pre-polymerization of a solid Ziegler-Natta catalyst component with a C2 to C4 olefin monomer before feeding to the continuous multi-stage process, and wherein the pre-polymerized solid Ziegler-Natta catalyst has a particle size distribution span ((d90-d10)/d50) of below 1.5.
Dependencies are inferred from the claim text.