Microporous aluminotitanosilicate crystalline zeolite, method of preparation and applications thereof

A microporous aluminotitanosilicate crystalline zeolite having a three-dimensional framework of A1O2, SiO2 and TiO2 tetrahedral units and an empirical composition in the as synthesized and anhydrous basis expressed by an empirical formula of:

• TipMmn+AlxSiOy
• wherein:
• p is the mole ratio of Ti to Si and has a value from 0.005 to about 0.1,
• M represents a potassium ion and/or sodium ion, or their exchangeable cations,
• m is the mole ratio of M to Si and varies from about 0.001 to about 0.05,
• n is the valence of M,
• x is the mole ratio of Al to Si and varies from 0.0025 to about 0.1;
• and
• y has a value determined by the equation:
• y=(4·p+m·n+3·x+4)/2
• and is characterized in that it has the x-ray diffraction pattern having at least the intensities set forth in Table A:
• TABLE A
• 2θ(Degree)
• I/Io %
• 6.45-6.8
• m
• 6.75-7.13
• m-vs
• 7.86-8.26
• m
• 8.64-9.04
• m
• 9.51-10.09
• m-vs
• 10.62-11.23
• w-m
• 13.4-14.22
• w-m
• 14.76-15.55
• w
• 17.63-18.37
• m
• 19.17-19.91
• w-m
• 19.64-20.56
• m
• 20.18-21.05
• w-m
• 20.7-21.57
• w-m
• 21.36-22.28
• vs
• 22.17-23.6
• m-s
• 22.7-23.8
• w-m
• 24.12-25.23
• w
• 25.6-26.94
• m
• 26.37-27.79
• m
• 27.02-28.42
• m
• 27.53-28.89
• m
• 28.7-30.09
• m
• 29.18-30.72
• w-m
• 30.19-31.73
• m
• 30.83-32.2
• w
• 32.81-34.22
• w
• 35.63-36.99
• w
• 41.03-42.86
• w
• 44.18-45.83
• w
• 44.87-46.57
• w
• 46.07-47.35
• w
• 48.97-50.42
• w
• wherein:
• the ratio of MSE framework characteristic peak intensity at a 2θ angle equal to 21.7 degree, to MFI framework characteristic peak intensity at a 2θ angle equal to 23.3 degree ranges from 80:1 to 1:1 in x-ray diffraction pattern.