Mixed-metal strategy for the fast synthesis of metal-organic frameworks under ambient conditions
AssigneeNational University of Singapore
InventorsDan Zhao, Shing Bo Peh, Avishek Karmakar
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Abstract
Disclosed herein is a metal organic framework (MOF) having a UTSA-16 structure, where the composition comprises: from 0 to 80 mol % of the total metal in the MOF is a first metal selected from one or more of the group consisting of Cr, Mn, Fe, Ni, Cu, and Co; and from 20 to 100 mol % of the total metal in the MOF is a second metal selected from one or more of the group consisting of Cd, Mn, and Zn.
Claims20
A metal organic framework (MOF) having a UTSA-16 structure, where the MOF comprises a first metal selected from one or more of the group consisting of Cr, Fe, Ni, Cu, and Co, wherein the first metal represents up to 80 mol % of the total metal in the MOF;
- and from 20 to 80 mol % of the total metal in the MOF is a second metal selected from one or more of the group consisting of Cd, Mn, and Zn, wherein the MOF comprises tetrahedral metal sites and a majority of the second metal occupies the tetrahedral metal sites within the MOF.
Dependencies are inferred from the claim text.