Method and installation for cryogenic separation of a gaseous mixture by methane scrubbing
AssigneeL'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
InventorsJean Billy, Axelle Gaertner, Antoine Hernandez, Jean-Marc Tsevery, Marie-Pascal Victor
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Abstract
In a process for the combined production of a) a hydrogen-enriched gas and a carbon monoxide-enriched gas and/or b) a mixture of hydrogen and carbon monoxide by cryogenic distillation and scrubbing, a still liquor is extracted from a scrubbing column and sent to a stripping column, a still liquor is extracted from the stripping column and sent to a separating column for carbon monoxide and methane and a cooling fluid is used at a pressure greater than that of the head of the separating column for cooling at least one fluid extracted at an intermediate level from the scrubbing column.
Claims11
A process for a combined production of i) a hydrogen-enriched gas and a carbon monoxide-enriched gas and/or ii) a mixture of hydrogen and carbon monoxide by cryogenic distillation and scrubbing, the process comprising the steps of:
- a. cooling a gaseous mixture comprising hydrogen, carbon monoxide, and methane in a heat exchanger to form a cooled mixture;
- b. sending the cooled mixture to a scrubbing column;
- c. introducing a methane-rich liquid into the scrubbing column as scrubbing liquid;
- d. withdrawing a hydrogen-enriched gas from the scrubbing column;
- e. withdrawing a first vessel liquid from the scrubbing column and sending said first vessel liquid to a stripping column;
- f. withdrawing a second vessel liquid from the stripping column and sending the second vessel liquid to a separation column that is configured to separate carbon monoxide and methane;
- g. withdrawing a first carbon monoxide-rich fluid from a volume located above a top of the separation column;
- h. withdrawing a second carbon monoxide-rich fluid from the volume located above the top of the separation column;
- i. expanding the second carbon monoxide-rich fluid to an expanded pressure (PE) and then warming the second carbon monoxide-rich fluid in the heat exchanger to form an expanded carbon monoxide gas;
- j. introducing the expanded carbon monoxide gas into an inlet stage of a centrifugal compressor;
- and
- k. using the first carbon monoxide-rich fluid as coolant fluid for cooling at least one fluid drawn off at an intermediate level of the scrubbing column,
- wherein at least a portion of a third vessel liquid from the separation column constitutes the methane-rich liquid of the step c,
- wherein the coolant fluid is at a greater pressure than that of the top of the separation column and the expanded pressure (PE), and in that the coolant fluid, after having served to cool the at least one fluid drawn off at the intermediate level of the scrubbing column, is sent to an intermediate stage of the centrifugal compressor at a pressure exceeding the expanded pressure (PE) in order to be compressed therein, such that the coolant fluid and the expanded carbon monoxide gas are introduced at different stages of the centrifugal compressor with the inlet stage being at a lower pressure than the intermediate stage.
A process for a combined production of i) a hydrogen-enriched gas and a carbon monoxide-enriched gas and/or ii) a mixture of hydrogen and carbon monoxide by cryogenic distillation and scrubbing, the process comprising the steps of:
- a. cooling a gaseous mixture comprising hydrogen, carbon monoxide, and methane in a heat exchanger to form a cooled mixture;
- b. sending the cooled mixture to a scrubbing column;
- c. introducing a methane-rich liquid into the scrubbing column as a scrubbing liquid;
- d. withdrawing a hydrogen-enriched gas from the scrubbing column;
- e. withdrawing a first vessel liquid from the scrubbing column and sending said first vessel liquid to a stripping column;
- f. withdrawing a second vessel liquid from the stripping column and sending the second vessel liquid to a separation column that is configured to separate carbon monoxide and methane;
- and
- g. withdrawing a first carbon monoxide-rich fluid from a volume located above a top of the separation column;
- h. using the first carbon monoxide-rich fluid as a coolant fluid for cooling at least one fluid drawn off at an intermediate level of the scrubbing column;
- and
- i. cooling a carbon monoxide stream in the heat exchanger and then introducing the carbon monoxide stream into an inlet stage of the centrifugal compressor, the carbon monoxide stream being at a first pressure,
- wherein the carbon monoxide stream is comprised of carbon monoxide sourced from a location selected from the group consisting of the top of the separation column, the volume located above the top of the separation column, and combinations thereof,
- wherein at least a portion of a third vessel liquid from the separation column constitutes the methane-rich liquid of the step c,
- wherein the coolant fluid is at a greater pressure than that of the top of the separation column and the first pressure, and in that the coolant fluid, after having served to cool the at least one fluid drawn off at the intermediate level of the scrubbing column, is sent to an intermediate stage of the centrifugal compressor at a pressure exceeding the first pressure in order to be compressed therein, such that the coolant fluid and the carbon monoxide stream are introduced at different stages of the centrifugal compressor with the inlet stage being at a lower pressure than the intermediate stage.
Dependencies are inferred from the claim text.