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US 11,444,250 B2Granted
Composition of matter for use in organic light-emitting diodes
AssigneeKyulux, Inc.
InventorsYoshitake Suzuki, Shuo-Hsien Cheng, Yu Seok Yang, Jorge Aguilera-Iparraguirre, Rafael Gomez-Bombarelli, Timothy D. Hirzel
Life of this patent
Estimating the term…
Abstract
The present disclosure relates to compounds of Formula (I) as compounds capable of emitting delayed fluorescence, and uses of the compounds in organic light-emitting diodes.
Claims22
A compound of Formula (I):
- wherein
- A is selected from CN
- X1, X2, X3, and X4 are independently selected from H, CN, F, CF3, SO2Ph, SO2Me, and NO2 provided that when A is CN and X2 is F or CF3, then X3 is F, or that when both A and X2 are CN, then X3 is H, F, CF3, SO2Ph, SO2Me, or NO2;
- at least one instance of X1, X2, X3, and X4 is not H;
- R1, R2, R3, R4, and R5 are independently selected from H, deuterium, Ph, and D;
- provided that R2 and R4 are not D;
- D is independently selected from
- R11 to R18 and R31 to R38 each independently represent a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl, a substituted or unsubstituted alkenyl, a substituted or unsubstituted alkynyl, CN, a substituted or unsubstituted aryl, a substituted or unsubstituted heteroaryl, or a substituted or unsubstituted diarylamine;
- each of R11 and R12, R12 and R13, R13 and R14, R15 and R16, R16 and R17, R17 and R18, L11 and R11, L11 and R18 taken together can form a ring system;
- each of R31 and R32, R32 and R33, R33 and R34, R35 and R36, R36 and R37, R37 and R38, L13 and R31, L13 and R38 taken together can form a ring system;
- L11 and L13 each independently represents a single bond, a substituted or unsubstituted arylene, or a substituted or unsubstituted heteroarylene;
- X represents O, S, a substituted or unsubstituted nitrogen atom, a substituted or unsubstituted carbon atom, a substituted or unsubstituted silicon atom, a carbonyl, a divalent substituted or unsubstituted ethylene having a bonding chain length of 2 atoms, a substituted or unsubstituted vinylene;
- a substituted or unsubstituted o-arylene, or a substituted or unsubstituted o-heteroarylene;
- and
- Y represents C or N, and no more than one instance of Y is N;
- n is 1;
- provided that if an instance of Y is N, then the corresponding substituent selected from to R31 to R34 is absent,
- provided that at least one of the following conditions (a) to (c) is satisfied:
- (a) A is selected from A1 to A13, and X1, X2, X3, and X4 are independently selected from CN, F, CF3, SO2Ph, SO2Me, and NO2,
- (b) X1, X2, X3, and X4 are independently selected from H, F, CF3, SO2Ph, SO2Me, and NO2, and at least one instance of R1, R3, and R5 is D, and
- (c) D is independently D-II, and at least one instance of R1, R3, and R5 is D.
18 more elements
Dependencies are inferred from the claim text.