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US 11,441,229 B2Granted
Method for selectively removing nickel platinum material
AssigneeEntegris, Inc.
InventorSeongJin Hong
Life of this patent
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Abstract
A method of selectively removing NiPt material from a microelectronic substrate, the method comprising contacting the NiPt material with an aqueous etching composition comprising: an oxidising agent; a strong acid; and a source of chloride.
Claims11
A method of selectively removing NiPt material from a microelectronic substrate including NiPt and NiPt silicide, the method comprising;
- i) contacting the NiPt material with an aqueous etching composition comprising:
- from 0.1 to 5 wt %, based on the total weight of the composition, of an oxidizing agent component, wherein the oxidizing agent component is hydrogen peroxide (H2O2);
- from 1 wt % to 20 wt %, based on the total weight of the composition, of a strong acid component selected from the group consisting of sulfuric acid, methanesulfonic acid, and combinations thereof;
- from 1 wt % to 6 wt %, based on the total weight of the composition, of a source of chloride component selected from the group consisting of ammonium chloride, HCl, and combinations thereof;
- and
- from 70 to 95 wt %, based on the total weight of the composition, of water,
- wherein the strong acid component and the source of chloride component are present in a ratio of 5:1 to 1:5,
- wherein the oxidizing agent component and strong acid component are present in a ratio of 5:1 to 1:5, and
- wherein the oxidizing agent component and source of chloride component are present in a ratio of 5:1 to 1:5;
- and
- ii) selectively removing the NiPt relative to the NiPt silicide with a NiPt etch rate of at least 100 Å/min, a NiPt silicide etch rate of at most 10 Å/min, and with a selectivity ratio of at least 40:1.
8 more elements
Dependencies are inferred from the claim text.