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US 11,441,024 B2Granted
Process for preparing a polypropylene composition
AssigneeBorealis AG
InventorsJingbo Wang, Markus Gahleitner, Elisabeth Potter, Jani Aho, Klaus Bernreitner, Luc Monnissen, Meta Cigon
Life of this patent
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Abstract
The invention relates to a process for producing a polypropylene composition having an improved balanced combination of high flowability, high stiffness and impact, and high level of optical properties. Further, the invention relates to the polypropylene composition having the above-mentioned properties, as well as an article comprising the polypropylene composition.
Claims14
A process for producing a polypropylene composition by sequential polymerization, the process comprising the steps of:
- a) polymerizing in a first reactor monomers comprising propylene and optionally one or more comonomers selected from ethylene and C4-C10 alpha-olefins, to obtain a first propylene polymer fraction having a comonomer content in the range of 0.0 to 1.0 wt %,
- b) polymerizing in a second reactor monomers comprising propylene and one or more comonomers selected from ethylene and C4-C10 alpha-olefins, in the presence of the first propylene polymer fraction to obtain a second propylene polymer fraction having a comonomer content in the range of from 4.5 to 20.0 wt %,
- c) pelletizing the second propylene polymer fraction, and
- d) melt-mixing the pelletized second propylene polymer fraction in the presence of:
- i. a propylene polymer (PP-c) produced in a process comprising at least two reactors connected in series, the propylene polymer (PP-c) containing one or more comonomers selected from ethylene and C4-C10 alpha-olefins wherein the comonomer content is in the range of from 0.5 to 2.5 wt %, and
- ii. at least one alpha-nucleating agent,
- wherein the polypropylene composition has:
- i—an MFR2 in the range of from 11.0 to 60.0 g/10 min, as measured according to ISO 1133 at 230° C. under a load of 2.16 kg;
- ii—a haze value of <20%, as measured according to ASTM D1003 on injection moulded plaques having 1 mm thickness produced as described in EN ISO 1873-2;
- iii—a tensile modulus >950 MPa, as measured according to ISO 527-1:2012/ISO 527-2:2012 on an injection moulded test specimen at 23° C.;
- iv—15 to 84 wt % of the pelletized second polymer fraction relative to the total amount of polypropylene composition;
- v—15 to 84% of the propylene polymer (PP-c) relative to the total amount of polypropylene composition;
- and
- vi—0.01 to 1.0 wt % of at least one alpha-nucleating agent relative to the total amount of polypropylene composition.
11 more elements
Dependencies are inferred from the claim text.