Polyarylene sulfide copolymer and method of producing the same
AssigneeToray Industries, Inc.
InventorsYuichiro Miyahara, Yuji Yamanaka, Takeshi Unohara
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Abstract
A polyarylene sulfide copolymer has a glass transition temperature of 95° C. or higher and 190° C. or lower and has a melting point of 300° C. or lower or does not have a melting point, as measured by differential scanning calorimetry, and the copolymer containing as a structural unit arylene sulfide units having a number average molecular weight (Mn) of 1,000 or more and 10,000 or less. The polyarylene sulfide copolymer can be provided with high physical stability such as in rigidity at high temperature and excellent moldability and chemical resistance.
Claims15
A polyarylene sulfide copolymer having a glass transition temperature of 95° C. or higher and 190° C. or lower, and having a melting point of 300° C. or lower, as measured by differential scanning calorimetry,
- wherein the copolymer comprises as a structural unit arylene sulfide units having a number average molecular weight (Mn) of 1,000 or more and 10,000 or less,
- the arylene sulfide units are represented as repeating units —(Ar—S)— and a copolymeric component,
- the copolymer contains 80 mol % or more of the repeating units represented by —(Ar—S)—, and
- a crystallized film of the polyarylene sulfide copolymer prepared by sandwiching a sample of the polyarylene sulfide copolymer and a spacer sandwiched between polyimide films,
- sandwiching the sample together with polyimide films between press molds that are heated to a melting point of the sample+30° C., and pressurized for 1 minute, after one-minute pressurization and retention, removing the sample together with the polyimide films and sandwiched between metal plates that is heated to a glass transition temperature+30° C. and pressurized for 5 minutes for crystallization to obtain the crystallized film, is immersed in N-methyl-2-pyrrolidone (NMP) that is heated to 80° C., and after keeping the liquid temperature at 80° C. for 20 minutes, the crystallized film is insoluble.
Dependencies are inferred from the claim text.