Preparation method for fumaric acid pour point depressant for crude oil
AssigneesDeshi Energy Technology Group Co., Ltd., Shandong Deshi Chemical Company Limited
InventorsShizhang Cui, Zongming Xiu, Liming Wang, Xinwang Song, Ruimei Gao, Yunfu Hou, Zhifeng Lv
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Abstract
A fumaric acid pour point depressant for crude oil and a preparation method therefor are provided. The fumaric acid pour point depressant is obtained by polymerizing a first prepolymer, a second prepolymer, a third monomer and a fourth monomer, where the first prepolymer is obtained by pre-polymerizing vinyl acetate and a first monomer; and the second prepolymer is obtained by pre-polymerizing fumaric acid and a second monomer.
Claims5
A preparation method for a fumaric acid pour point depressant for crude oil, comprising the following steps:
- pre-polymerizing vinyl acetate and a first monomer having a weight ratio of (1-10):1 to obtain a first prepolymer with a degree of polymerization of 20-40;
- pre-polymerizing fumaric acid and a second monomer having a weight ratio of (10-50):1 to obtain a second prepolymer with a degree of polymerization of 18-50;
- and
- adding a third monomer to the second prepolymer, performing esterification for no more than 1 hour, then adding the first prepolymer and a fourth monomer, and performing polymerization for at least 3 hours to obtain the fumaric acid pour point depressant for crude oil;
- the first prepolymer, the second prepolymer, the third monomer and the fourth monomer have a weight ratio of (5-25):(10-80):(5-20):(2-25);
- the first monomer is a mixture of N-vinylpyrrolidone and 2-(N-acryloyloxy)ethylpyrrolidone;
- and the N-vinylpyrrolidone and the 2-(N-acryloyloxy)ethylpyrrolidone have a weight ratio of (1-6):1;
- the second monomer is a mixture of allyl polyether and allyl alcohol polyether;
- and the allyl polyether and the allyl alcohol polyether have a weight ratio of 1:(10-35);
- the third monomer is a mixture of tetradecanol, hexadecanol, octadecanol and eicosanol;
- and the tetradecanol, the hexadecanol, the octadecanol and the eicosanol have a weight ratio of (1-10):1:(1-5):(1-5);
- the fourth monomer is a mixture of acrylamide and N-(hydroxymethyl)acrylamide;
- and the acrylamide and the N-(hydroxymethyl)acrylamide have a weight ratio of (1-15):1.
Dependencies are inferred from the claim text.