A method of sputtering a layer on a substrate using magnetically enhanced plasma, the method comprising:
- forming a gap between a hollow cathode target assembly and an anode on top of the hollow cathode target assembly;
- generating a magnetic field in the gap such that magnetic field lines are substantially perpendicular to a surface of the hollow cathode target assembly;
- connecting a pulse power supply to an electrode positioned behind the gap;
- providing radio frequency (RF) power to the hollow cathode target assembly that ignites and sustains volume discharge in the hollow cathode target assembly;
- and
- generating a train of voltage pulses comprising a frequency, duration, and amplitude selected to increase a degree of dissociation of feed gas molecules to form the layer from sputtering hollow cathode target material onto the substrate.