Transfer hydrogenation of heavy hydrocarbons with hydrogen-donor solvents
AssigneeBattelle Memorial Institute
InventorsSatya P. Chauhan, Daniel B. Garbark
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Abstract
Processes for treating highly viscous hydrocarbons, such as bitumen from oil sands or petroleum residues, with hydrogen-donor solvents are described. The hydrogen-donor solvent is prepared. A mixture of the hydrocarbon and the hydrogen-donor solvent is heated, and the product is cooled to produce a low viscosity and mildly upgraded hydrocarbon. The hydrogen-donor solvent can be modified to improve its solvent usefulness.
Claims16
A process of thermally treating a highly viscous, heavy hydrocarbon comprising:
- preparing a hydrogen-donor solvent capable of dehydrogenation;
- mixing the heavy hydrocarbon and the hydrogen-donor solvent to form a slurry;
- heating the slurry such that the heavy hydrocarbon depolymerizes to form smaller fragments and wherein the hydrogen-donor solvent transfers hydrogen to the smaller fragments to prevent repolymerization of the smaller fragments;
- and
- cooling the product wherein the product comprises a hydrocarbon having a lower viscosity than a viscosity of the heavy hydrocarbon;
- wherein the heavy hydrocarbon is treated without using molecular hydrogen and an added catalyst.
The process of claim I wherein the hydrogen-donor solvent contains compounds that can dehydrogenate during hydrocarbon treatment.
Dependencies are inferred from the claim text.