Addition-curable silicone rubber composition
AssigneeMomentive Performance Materials Inc.
InventorsHuiping Zhang, Srividhya Marimuthu, Gunnar Hoffmueller, John Mitchell Huggins, Enise Michalski
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Abstract
The present invention relates to an addition-curable silicone rubber composition having self-bonding capability. The addition-curable silicone rubber composition exhibits self-bonding capability in particular to substrates that contain residual hydroxyl groups or other residual hydrosilyl-reacting groups on their surface, including polycarbonate, polyester, polyamide, polysulfone, polyurethane, phenolic resin, epoxy resin, cellulose, glass and the mixture thereof.
Claims17
An addition-curable silicone rubber composition, comprising:
- (A) at least one polyorganosiloxane having at least two unsaturated hydrocarbyl residues,
- (B) at least one polyorganohydrogensiloxane selected from one or more polyorganohydrogensiloxanes of the general formula (2):
- [M1a2D1b2T1c2Qd2Ze2]m2 (2)
- wherein the siloxy units
- M=R3SiO1/2, or M**
- D=R2SiO2/2, or D**
- T=RSiO3/2, or T**
- Q=SiO4/2,
- M**=HR2SiO1/2, D**=HRSiO2/2, T**=HSiO3/2,
- Z is a divalent optionally substituted hydrocarbyl bridging group with up to 14 carbon atoms between two siloxy groups as defined before,
- wherein R is selected from optionally substituted hydrocarbyl groups with up to 30 carbon atoms and poly(C2-C4)-alkylene ether groups with up to 1000 alkylene oxy units. the groups R being free of aliphatic unsaturation, and wherein
- a2=2-10
- b2=0-1000
- c2=0-50
- d2=0-5
- m2=1-1000,
- with the proviso that there are at least two groups selected from M**, D** and T**,
- (C) at least one hydrosilylation catalyst, comprising a transition metal,
- (D) at least one organosilicon compound containing at least one polyvalent aromatic group, which is not directly attached to a silicon atom, and at least one Si-H group, different from compound B),
- (E) at least one aromatic compound with at least two unsaturated hydrocarbyl groups, which aromatic compound does not contain a siloxane group, and does not contain an ester group,
- (F) optionally one or more reinforcing fillers,
- (G) optionally one or more auxiliary additives.
Dependencies are inferred from the claim text.