Polylactic acid resin composition and polylactic acid resin molded article
AssigneeBioworks Corporation
InventorTakahiko Terada
Life of this patent
Estimating the term…
Abstract
A polylactic acid resin composition is obtained by melting a mixture containing 100 parts by weight of a poly-L-lactic acid (A) having an L-lactic acid purity of 99 mol % or more, 2.6 to 10 parts by weight of a plasticizer (B), and 0.3 to 1.0 part by weight of a lubricant (C), then cooling the mixture to 20 to 40° C., and then heating the mixture to 46 to 70° C., and satisfies the following conditions (a) and (b): (a) a haze value at a thickness of 0.3 mm is 5% or less; and (b) the degree of crystallinity measured by a differential scanning calorimeter is 50 to 70%.
Claims10
A polylactic acid resin composition obtained by melting a mixture comprising 100 parts by weight of a poly-L-lactic acid (A) having an L-lactic acid purity of 99 mol % or more, 2.6 to 10 parts by weight of a plasticizer (B), and 0.41 to 1.0 part by weight of a lubricant (C), then cooling the mixture to 20 to 40° C., and then heating the mixture to 46 to 70° C.,
- wherein the plasticizer (B) is at least one selected from the group consisting of polyethylene glycol and a castor oil-based fatty acid ester, or a mixture thereof,
- the lubricant (C) is at least one selected from the group consisting of ethylene bishydroxystearic acid amide, N-stearyl erucic acid amide, N-stearyl stearic acid amide, and ethylene bisstearic acid amide, or a mixture thereof, and
- the following conditions (a) and (b) are satisfied:
- (a) a haze value at a thickness of 0.3 mm is 5% or less;
- and
- (b) the degree of crystallinity measured by a differential scanning calorimeter is 50 to 70%,
- wherein the degree of crystallinity is obtained by measuring crystallization heat quantity (ΔHc) and melting heat quantity (ΔHm) when the polylactic acid resin composition is heated at a rate of 10° C./min using a differential scanning calorimeter (DSC) and performing a calculation according the following formula:
- degree of crystallinity=(melting heat quantity−crystallization heat quantity)/93×100.
A polylactic acid resin molded article obtained by further heating the polylactic acid resin composition according to claims 1 to 130 to 160° C. to soften the composition, and then molding and cooling the composition in a die.
Dependencies are inferred from the claim text.