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US 11,299,609 B2Granted
Blends of linear low density polyethylenes
AssigneeUnivation Technologies, LLC
InventorsSwapnil B. Chandak, Nitin Borse
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Abstract
A polyethylene blend comprising a uniform dispersion of constituents (A) and (B): (A) a Ziegler-Natta catalyst-made linear low density polyethylene and (B) a metallocene catalyst-made linear low density polyethylene, a composition comprising the polyethylene blend and at least one additive, methods of making and using same, and manufactured articles and films comprising or made from same.
Claims9
A polyethylene blend comprising a uniform dispersion of constituents (A) and (B):
- (A) a Ziegler-Natta catalyst-made linear low density polyethylene (ZN-LLDPE) and (B) a metallocene catalyst-made linear low density polyethylene (MCN-LLDPE);
- wherein the (A) ZN-LLDPE is from 25 to 50 weight percent (wt %) of the total weight of (A) and (B) and the (B) MCN-LLDPE is from 75 to 50 wt % of the total weight of (A) and (B);
- wherein by itself (A) independently has each of properties (i) to (iii):
- (i) a melt index (“I2”, 190° C., 2.16 kg) of 0.9 to 1.1 gram per 10 minutes (g/10 min.) measured according to ASTM D1238-04;
- (ii) a density of 0.918±0.003 gram per cubic centimeter (g/cm3), measured according to ASTM D792-13;
- and (iii) no detectable amount of long chain branching per 1,000 carbon atoms (“LCB Index”), measured according to LCB Test Method;
- and wherein by itself (B) independently has each of properties (i) to (iii):
- (i) a melt index (“I2”, 190° C., 2.16 kg) of 0.9 to 1.1 g/10 min. measured according to ASTM D1238-04;
- (ii) a density of 0.918±0.003 g/cm3, measured according to ASTM D792-13;
- and (iii) no detectable amount of long chain branching per 1,000 carbon atoms (“LCB Index”), measured according to LCB Test Method;
- and with the proviso that the density of constituent (B) is within ±0.001 g/cm3 of the density of constituent (A);
- wherein the (A) ZN-LLDPE is made by copolymerizing ethylene and 1-hexene in the presence of the Ziegler-Natta catalyst and the (B) MCN-LLDPE is made by copolymerizing ethylene and 1-hexene in the presence of the metallocene catalyst;
- and
- wherein the melt index (“I2”, 190° C., 2.16 kg) of constituent (B) is within ±0.1 g/10 min. of the melt index (“I2”, 190° C., 2.16 kg) of constituent (A);
- and
- wherein when formed as a film having a thickness of 0.0127 millimeter the film has a puncture resistance, measured according to ASTM D5748-95(2012), of at least 24.8 Joules per cubic centimeter (J/cm3).
13 more elements
Dependencies are inferred from the claim text.