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US 11,299,454 B2Granted
Method of producing N-vinylcarboxylic acid amide
AssigneeShowa Denko K.K.
InventorNaoyuki Tanaka
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Abstract
A method for producing an N-vinylcarboxylic acid amide is provided, the method focusing on unsaturated aldehydes that are contained as impurities generated during a reaction. The method for producing an N-vinylcarboxylic acid amide includes a step for controlling the contained amount of unsaturated aldehydes in the N-vinylcarboxylic acid amide to be not more than 20 mass ppm.
Claims5
A method of producing N-vinylcarboxylic acid amide, comprising:
- a step of obtaining N-vinylcarboxylic acid amide by using the de-alcoholization reaction from N-(1-alkoxyethyl) carboxylic acid amide,
- wherein the N-(1-alkoxyethyl) carboxylic acid amide is a compound represented by the following general formula (I),
- wherein R1 represents an alkyl group having 1 to 5 carbon atoms, R2 independently represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, and R3 represents an alkyl group having 1 to 5 carbon atoms;
- and
- a step of controlling an amount of unsaturated aldehydes in N-vinylcarboxylic acid amide to 20 mass ppm or less,
- wherein the step of controlling an amount of unsaturated aldehydes comprises steps of
- obtaining a second crude N-(1-alkoxyethyl) carboxylic acid amide by adjusting a pH of a first crude N-(1-alkoxyethyl) carboxylic acid amide to 8.0 to 8.5 by using 30 to 48% by mass of one selected from the group consisting of a sodium hydroxide aqueous solution and a potassium hydroxide aqueous solution;
- and
- purifying the N-(1-alkoxyethyl) carboxylic acid amide by distilling the second crude N-(1-alkoxyethyl) carboxylic acid amide.
6 more elements
Dependencies are inferred from the claim text.