Thickening anionic copolymer
AssigneeCoatex
InventorsYves Matter, Jean-Marc Suau, Francis Bony, Francois Dupont
Life of this patent
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Abstract
The invention relates to a copolymer obtained by polymerisation reaction of at least three comonomers: a first anionic monomer, a second monomer comprising an olefin unsaturation, and a third monomer comprising a hydrophobic group. The invention likewise relates to the use of said copolymer as a thickening agent, in particular in aqueous suspensions of mineral particles with high solids content. The copolymer according to the invention makes it possible to improve the compromise between viscosity with high shear gradient and viscosity with low shear gradient, while also improving water retention inside the suspension.
Claims15
A copolymer (P1), obtained by a polymerization reaction of a monomer composition consisting of:
- (a1) 5% to 30% by weight, based on the total amount by weight of monomers, at least one anionic monomer selected from the group consisting of acrylic acid and methacrylic acid,
- (b1) 65% to 90% by weight, based on the total amount by weight of monomers, at least one monomer of formula (I):
- in which:
- R1 and R2, which are identical or different, independently represent H or CH3,
- L1 independently represents a group chosen from C(O), CH2 and CH2—CH2,
- L2 independently represents a group chosen from (CH2—CH2O)x, (CH(CH3)CH2O)y and combinations thereof, and
- x and y, which are identical or different, independently represent 0 or an integer or decimal number between 0.1 and 150, wherein x is strictly greater than y and the sum x+y is between 10 and 150, and
- (c1) 0.5% to 30% by weight, based on the total amount by weight of monomers, at least one monomer of formula (II):
- in which:
- R3 independently represents a functional group derived from a compound selected from the group consisting of acrylate, methacrylate, acrylurethane and methacrylurethane,
- R4 independently represents a saturated, linear hydrocarbon group comprising from 6 to 40 carbon atoms, an unsaturated linear hydrocarbon group comprising from 6 to 40 carbon atoms, a saturated branched hydrocarbon group comprising from 6 to 40 carbon atoms, an unsaturated branched hydrocarbon group comprising from 6 to 40 carbon atoms, a saturated cyclic hydrocarbon group comprising from 6 to 40 carbon atoms, an unsaturated cyclic hydrocarbon group comprising from 6 to 40 carbon atoms, or an aromatic hydrocarbon group comprising from 6 to 40 carbon atoms,
- L3 independently represents a group chosen from (OCH2—CH2)m, (OCH(CH3)CH2)n and combinations thereof, and
- m and n, which are identical or different, independently represent 0 or an integer or decimal number between 0.1 and 150, wherein m is strictly greater than n and the sum m+n is between 10 and 150, and
- (d1) optionally 0.1% to 7% by weight, based on the total amount by weight of monomers, of at least one additional monomer selected from the group consisting of 2-acrylamido-2-methylpropanesulfonic acid, 2-sulfoethyl methacrylate, sodium methallylsulfonate, and styrenesulfonate, or a salt thereof, and
- (e1) optionally 0.01% to 5% by weight, based on the total amount by weight of monomers, of at least one crosslinking monomer or at least one monomer comprising at least two olefinic unsaturations.
Dependencies are inferred from the claim text.