Additives for low-sulfur marine diesel
AssigneeClariant International Ltd.
InventorsMichael Feustel, Matthias Krull, Michael Morscher
Life of this patent
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Abstract
This invention relates to a fuel oil composition, containing a low-sulfur marine diesel having a sulfur content of less than 1 wt. % and (A) at least one ethylene copolymer and (B) at least one comb polymer.
Claims28
A fuel oil composition comprising a low-sulfur marine diesel having a sulfur content of less than 1% by weight and
- (A) at least one ethylene copolymer containing, as well as ethylene, 8.0 to 17 mol % of one or more vinyl and/or (meth)acrylic esters, and
- (B) at least one comb polymer (B) comprising structural units B1 which derive from C10-C28-alkyl esters of unsaturated mono- and dicarboxylic acids, C10-C28-alkyl vinyl esters, C10-C28-alkyl vinyl ethers, C10-C28-alkyl allyl ethers and/or linear C12-C30-α-olefins, and wherein at least 20 mol % of the alkyl radicals bonded to the repeat structural units (B1) have 12 to 16 carbon atoms and at least 5 mol % of the alkyl radicals have 18 or more carbon atoms, in which the untreated low-sulfur marine diesel has a pour point of +6° C. or higher.
A method of dispersing paraffins which precipitate out of low-sulfur marine diesel having a sulfur content of 1% by weight or lower on storage at temperatures below the cloud point, by adding to the low-sulfur marine diesel an ethylene copolymer (A) containing, as well as ethylene, 8.0 to 17 mol % of one or more vinyl and/or (meth)acrylic esters, and a comb polymer (B) comprising structural units B1 which derive from C10-C28-alkyl esters of unsaturated mono- and dicarboxylic acids, C10-C28-alkyl vinyl esters, C10-C28-alkyl vinyl ethers, C10-C28-alkyl allyl ethers and/or linear C12-C30-α-olefins, and wherein at least 20 mol % of the alkyl radicals bonded to the repeat structural units (B1) have 12 to 16 carbon atoms and at least 5 mol % of the alkyl radicals have 18 or more carbon atoms, and in which the untreated low-sulfur marine diesel has a pour point of +6° C. or higher.
A method of dispersing paraffins which precipitate out of a low-sulfur marine diesel having a sulfur content of 1% by weight or lower on storage below the cloud point, wherein the low-sulfur marine diesel contains an ethylene copolymer (A), by adding a comb polymer (B) comprising structural units B1 which derive from C10-C28-alkyl esters of unsaturated mono- and dicarboxylic acids, C10-C28-alkyl vinyl esters, C10-C28-alkyl vinyl ethers, C10-C28-alkyl allyl ethers and/or linear C12-C30-α-olefins, and wherein at least 20 mol % of the alkyl radicals bonded to the repeat structural units (B1) have 12 to 16 carbon atoms and at least 5 mol % of the alkyl radicals have 18 or more carbon atoms, in which the untreated low-sulfur marine diesel has a pour point of +6° C. or higher, and in which the ethylene copolymer (A) contains, as well as ethylene, 8.0 to 17 mol % of one or more vinyl and/or (meth)acrylic esters.
Dependencies are inferred from the claim text.