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US 11,111,457 B2Granted
Lubricating oil composition
AssigneeIdemitsu Kosan Co., Ltd.
InventorToshiaki Iwai
Life of this patent
Estimating the term…
Abstract
Disclosed is a lubricating oil composition capable of inhibiting vibrations or noises generated between a pulley and a chain or between a pulley and a belt in a CVT or the like, while increasing an intermetallic friction coefficient, the composition containing a base oil, an alkaline earth metal-based detergent (A), a phosphite ester (B1), a phosphate ester amine salt (B2), an acidic phosphate ester (B3), an aliphatic monoamine (C1), and an aromatic monoamine (C2).
Claims8
A method to lubricate a continuously variable transmission (CVT), comprising:
- applying a lubricating oil composition between a pulley and a belt or between a pulley and a chain of the CVT;
- wherein the lubricating oil composition comprises:
- a base oil;
- (A) an alkaline earth metal-based detergent (A) having a base number of from 10 to 500 mgKOH/g as measured according to the perchloric acid method of JIS K-2501,
- wherein the amount of the alkaline earth metal atom derived from the alkaline earth metal-based detergent (A) is from 10 to 1,500 ppm by mass;
- (B1) 0.01 to 0.5% by mass of a phosphite ester (B1) represented by the following formula (I):
- (R1O)aP(OH)3-a (I)
- wherein R1 represents a hydrocarbon group having 2 to 24 carbon atoms;
- a represents an integer of 1 to 3;
- and when a is 2 or 3, R1's may be the same as or different from each other,
- (B2) 0.01 to 0.5% by mass of a phosphate ester amine salt (B2) which is an amine salt of an acidic phosphate ester represented by the following formula (II):
- (R2O)bP(═O)(OH)3-b (II)
- wherein R2 represents a hydrocarbon group having 2 to 24 carbon atoms;
- b represents an integer of 1 or 2;
- and when b is 2, R2's may be the same as or different from each other,
- (B3) 0.01 to 0.8% by mass of an acidic phosphate ester (B3) represented by the following formula (III):
- (R3O)cP(═O)(OH)3-c (III)
- wherein R3 represents a hydrocarbon group having 2 to 24 carbon atoms;
- c represents an integer of 1 or 2;
- and when c is 2, R3's may be the same as or different from each other,
- (C1) 0.01 to 0.8% by mass of an aliphatic monoamine (C1) represented by the following formula (IV):
- NR4R5R6 (IV)
- wherein R4 represents an aliphatic hydrocarbon group having 10 to 24 carbon atoms;
- R5 and R6 each represent a hydrogen atom or an alkyl group having 1 to 4 carbon atoms;
- and R5 and R6 may be the same as or different from each other, and
- (C2) 0.05 to 0.7% by mass of an aromatic monoamine (C2) represented by the following formula (V):
- NR7R8R9 (V)
- wherein R7 represents an aromatic hydrocarbon group having 6 to 12 carbon atoms;
- R8 and R9 each represent a hydrogen atom or an alkyl group having 1 to 4 carbon atoms;
- and R8 and R9 may be the same as or different from each other;
- and further wherein
- an intermetallic friction coefficient according to ASTM D2714 of the lubricating oil is 0.114 or more, wherein the test is run under the following conditions:
- <Breaking-in conditions>
- Surface pressure:
- 0.8 GPa
- Oil temperature:
- 90° C.
- Average slipping velocity:
- 0.500 m/s
- Time:
- 30 minutes
- <Measurement conditions>
- Surface pressure:
- 0.8 GPa
- Oil temperature:
- 90° C.
- Average slipping velocity:
- 0.500 m/s
- <Material of test piece>
- Steel-steel;
- and
- a ratio of intermetallic friction-coefficient/slipping-velocity according to ASTM D2714 of the lubricating oil is 1.03 or less wherein the test is run under the following conditions:
- <Breaking-in conditions>
- Surface pressure:
- 0.8 GPa
- Oil temperature:
- 90° C.
- Average slipping velocity:
- 0.500 m/s
- Time:
- 30 minutes
- <Measurement conditions>
- Surface pressure:
- 0.8 GPa
- Oil temperature:
- 90° C.
- Average slipping velocity:
- 0.025 m/s and 0.500 m/s
- <Material of test piece>
- Steel-steel
- <Calculation method μ ratio>
- μ Ratio=(Friction coefficient at 0.025 m/s)/(Friction coefficient at 0.500 m/s).
69 more elements
Dependencies are inferred from the claim text.