Polymerization processes

A polymerization process to produce a polyethylene polymer, the process comprising contacting a catalyst system comprising a product of a combination of one or more metallocene catalysts, at least one activator, and at least one support, with ethylene and one or more C3-C10 alpha-olefin comonomers under polymerizable conditions including a temperature range of from 10° C. to 75° C., to produce the polyethylene polymer;

• wherein the polyethylene polymer has a broad orthogonal composition distribution (BOCD) and furthermore has a density of from 0.890 g/cm3 to 0.950 g/cm3, and
• further wherein the one or more metallocene catalysts comprises:
• (A) a compound represented by Formula (I):
• TyCpmM6GnX5q (I),
• wherein each Cp is, independently, a cyclopentadienyl group which may be substituted or unsubstituted, M6 is a Group 4 transition metal, G is a heteroatom group represented by the Formula JR*z where J is N, and R* is methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, cyclooctyl, cyclododecyl, decyl, undecyl, dodecyl, adamantyl or an isomer thereof and z is 1 or 2, T is a bridging group, and y is 1, X5 is a leaving group, and m=1, n=1, q=0, 1, 2 or 3, and the sum of m+n+q is equal to the oxidation state of the transition metal;
• and/or
• (B) one or more of the following compounds:
• dimethylsilyl (tetramethylcyclopentadienyl)(cyclododecylamido)titanium dimethyl;
• dimethylsilyl (tetramethylcyclopentadienyl)(cyclododecylamido)titanium dichloride;
• dimethylsilyl (tetramethylcyclopentadienyl)(t-butylamido)titanium dimethyl;
• dimethylsilyl (tetramethylcyclopentadienyl)(t-butylamido)titanium dichloride;
• μ-(CH3)2Si(cyclopentadienyl)(1-adamantylamido)M7(R15)2;
• μ-(CH3)2Si(3-tertbutylcyclopentadienyl)(1-adamantylamido)M7(R15)2;
• μ-(CH3)2C(tetramethylcyclopentadienyl)(1-adamantylamido)M7(R15)2;
• μ-(CH3)2Si(tetramethylcyclopentadienyl)(1-adamantylamido)M7(R15)2;
• μ-(CH3)2C(tetramethylcyclopentadienyl)(1-tertbutylamido)M7(R15)2;
• μ-(CH3)2Si(tetramethylcyclopentadienyl)(1-tertbutylamido)M7(R15)2;
• μ-(CH3)2Si(fluorenyl)(1-tertbutylamido)M7(R15)2;
• μ-(CH3)2Si(tetramethylcyclopentadienyl)(1-cyclododecylamido)M7(R15)2;
• or
• μ-(C6H5)2C(tetramethylcyclopentadienyl)(1-cyclododecylamido)M7(R15)2,
• where M7 is selected from a group consisting of Ti, Zr, and Hf and R15 is selected from halogen or C1-C5 alkyl.