Tie layer compositions and multilayer films incorporating the same
AssigneeDow Global Technologies LLC
InventorsSydney E. Hansen, Brian W. Walther, Hayley A. Brown, Santosh S. Bawiskar
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Abstract
Embodiments are directed to a tie layer composition comprising functionalized polyethylene, styrene block copolymer, base polyethylene, and antioxidant co-stabilizers, wherein the antioxidant co-stabilizers comprise at least one oxygen scavenger, at least one peroxy free radical scavenger, and at least one alkyl free radical scavenger. Further embodiments are directed to multilayer films or sheets which include the tie layer composition.
Claims16
A tie layer composition comprising
- functionalized polyethylene, styrene block copolymer, base polyethylene, and antioxidant co-stabilizers,
- wherein the antioxidant co-stabilizers comprise at least one oxygen scavenger comprising a phosphite, at least two peroxy free radical scavengers comprising sterically hindered phenolics, and at least one alkyl free radical scavenger comprising an acrylate, thereby demonstrating improved adhesion and viscosity control, and
- wherein the tie layer composition comprises from 3000 to 10,000 ppm of the antioxidant co-stabilizers including 1000 to 4300 ppm of the alkyl free radical scavenger.
A multilayer film comprising at least five layers, wherein the at least 5 layers comprise:
- at least one polyolefin outer layer;
- at least one polystyrene outer layer;
- at least one core layer disposed between the polyolefin outer layer and the polystyrene outer layer, the core layer comprising a polar polymer;
- a first tie layer disposed between the polyolefin outer layer and the core layer;
- and
- a second tie layer disposed between the polystyrene outer layer and the core layer,
- wherein the first tie layer, the second tie layer, or both comprises a tie layer composition comprising
- functionalized polyethylene, styrene block copolymer, base polyethylene, and antioxidant co-stabilizers,
- wherein the antioxidant co-stabilizers comprise at least one oxygen scavenger comprising a phosphite, at least two peroxy free radical scavengers comprising sterically hindered phenolics, and at least one alkyl free radical scavenger comprising an acrylate, thereby demonstrating improved adhesion and viscosity control, and
- wherein the tie layer composition comprises from 3000 to 10,000 ppm of the antioxidant co-stabilizers including 1000 to 4300 ppm of the alkyl free radical scavenger.
Dependencies are inferred from the claim text.