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US 11,077,711 B2Granted
Rubber composition and pneumatic tire
AssigneesThe Yokohama Rubber Co., Ltd., National University Corporation Kyoto Institute of Technology
InventorsWataru Sakai, Takuma Arikawa, Ryosuke Sakai, Yu Shinke, Yuko Sekine, Fumito Yatsuyanagi
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Abstract
A rubber composition of the present technology is a rubber composition including a diene rubber and a filler; the diene rubber containing at least a styrene-butadiene copolymer; a radical generation index of the styrene-butadiene copolymer being not greater than 1.0 and being smaller than a value Y calculated by Equation (1): Y=−0.0186×(SV mass %+vinyl unit mol %)+1.5.
Claims19
A rubber composition comprising a diene rubber and a filler;
- the diene rubber containing a styrene-butadiene copolymer and a natural rubber, wherein the content of the styrene-butadiene copolymer is not less than 40 mass % and less than 50 mass % of the total mass of the diene rubber;
- a radical generation index of the styrene-butadiene copolymer being not greater than 1.0 and being smaller than a value Y calculated from an equation:Y=−0.0186×(SV mass %+vinyl unit mol %)+1.5
- where the radical generation index is an index representation of a radical concentration using the radical concentration of a copolymer having a molar ratio of styrene units/1,2 vinyl units/1,4 trans units/1,4 cis units of 13/14/15/58 as a 1.0 reference value;
- and
- “SV mass %” in the equation is a mass % of a partial structure where a styrene single chain having one styrene unit and a vinyl single chain having one vinyl unit are directly linked relative to an amount of bonded styrene of the styrene-butadiene copolymer, and “vinyl unit mol %” in the equation is a mol % of vinyl units when a total of styrene units, 1,2 vinyl units, 1,4 trans units, and 1,4 cis units in the styrene-butadiene copolymer is defined as 100 mol %, and
- wherein the styrene single chain content having one styrene unit is not greater than 30 mass % of the amount of bonded styrene in the styrene-butadiene copolymer.
3 more elements
Dependencies are inferred from the claim text.