Continuous roll-to-roll process design for vertical alignment of particles using electric field

A method of preparing an anisotropic polymer film comprising:

• providing a polymer film on a transportable conveyor acting as a second electrode, the polymer film including an orientable component, wherein the orientable component is polymer phases, dispersed particles, or both polymer phases and dispersed particles, the polymer film having a thickness, where the polymer film is UV-curable, supplying an electric field across an electric field application zone, where the electric field is generated by a first electrode positioned above the second electrode and having a first charge, the second electrode having a charge opposite of the first electrode, where the first electrode is a belt wrapped around two rollers, where the belt is a transparent conductive film, rotating the first electrode through the electric field application zone at a rotation speed, transporting the second electrode through the electric field application zone at a transport speed to thereby pass the polymer film through the electric field application zone, where the step of transporting includes contacting the first electrode and the polymer film and inducing orientation of the orientable component, adjusting the height of the belt by moving a back plate that is connected to the two rollers, where the step of adjusting by moving the back plate maintains the contacting of the first electrode and the polymer film, the first electrode includes a voltage source in constant contact therewith, where the voltage source is spring loaded in order to maintain the constant contact, and freezing the polymer film, by applying a UV light, to lock the orientation of the orientable component during the step of transporting and before the polymer film exits the electric field application zone to thereby produce an oriented polymer film, where the orientation of the orientable component is in the direction of the polymer film thickness, where the UV light is positioned between the two rollers and within the wrapped belt.