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US 11,028,268 B2Granted
Process for producing compositions crosslinkable to elastomers
AssigneeWacker Chemie AG
InventorsTorsten Sixt, Franz Neuhauser, Josef Schnitzinger
Life of this patent
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Abstract
Neutral moisture curable organopolysiloxane compositions are prepared from silanol-stopped organopolysiloxanes, alkoxysilanes, aminosilanes, and ketoximino silanes, and contain less than 1 weight percent oximes upon storage.
Claims14
A process for producing moisture curable compositions crosslinkable to elastomers, comprising:
- in a first step, providing a mixture comprising
- (1) at least one organopolysiloxane having at least two hydroxyl groups,
- (2) at least one alkoxysilane of the formula
- RSi(OR1)3 (I),
- and/or partial hydrolysates thereof,
- where R is a monovalent hydrocarbyl radical having 1 to 18 carbon atoms, and
- R1 is identical or different and is a monovalent hydrocarbyl radical having 1 to 8 carbon atoms, and
- (3) organosilicon compounds having at least one radical containing basic nitrogen and bonded via carbon to silicon,
- in a second step, adding to the mixture of the first step
- (4) at least one ketoximosilane of the formula
- R2Si(ON═CR32)3 (II)
- and/or their partial hydrolysates,
- where R2 is a monovalent hydrocarbyl radical having 1 to 18 carbon atoms, and
- R3 is identical or different and is a monovalent hydrocarbyl radical having 1 to 5 carbon atoms, in amounts of at most 1 wt %, based on the total weight of the composition,
- and optionally adding further alkoxysilanes (2) and/or their partial hydrolysates and optionally further organosilicon compounds (3) in the second step or optionally in a third step subsequent to the second step, and adding and mixing
- (5) condensation catalysts,
- optionally
- (6) fillers,
- optionally
- (7) adhesion promoters,
- optionally
- (8) plasticizers,
- optionally
- (9) stabilizers, and
- optionally
- (10) additives different from components (1)-(9), wherein in the third step, further alkoxysilanes (2) of the formula (I) and/or their partial hydrolysates and further organosilicon compounds (3) are added to the reaction mixture from the second step.
23 more elements
Dependencies are inferred from the claim text.