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US 11,026,421 B2Granted
Efficient stabilizer in controlling self accelerated decomposition temperature of peroxycarboxylic acid compositions with mineral acids
AssigneeEcolab USA Inc.
InventorsJunzhong Li, David D. McSherry, Richard Staub
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Abstract
Highly acidic, stabilized peroxycarboxylic acid compositions are disclosed as having both improved antimicrobial efficacy in comparison to conventional peroxyoctanoic acid and peroxyacetic acid compositions for sanitizing applications, and improved transport and shipping stability. In particular, low odor and low/no VOC compositions having dual functionality as both acid wash and sanitizing compositions are disclosed.
Claims18
A stabilized homogenous equilibrium peracid composition comprising:
- a peroxycarboxylic acid mixture comprising a C1-C4 peroxycarboxylic acid and a C5-C22 peroxycarboxylic acid;
- a carboxylic acid mixture comprising a C1-C4 carboxylic acid and a C5-C22 carboxylic acid;
- hydrogen peroxide;
- about 12.5 wt. % to about 50 wt. % of a sulfuric acid, phosphoric acid, and/or methane sulfonic acid;
- a peroxycarboxylic acid stabilizing agent, wherein the stabilizing agent comprises a picolinic acid, or a compound having the following Formula (IA):
- wherein R is OH or —NR1aR1b, wherein R1a and R1b are independently hydrogen or (C1-C6)alkyl;
- wherein R2 is OH or NR2aR2b, wherein R2a and R2b are independently hydrogen or (C1-C6)alkyl;
- wherein each R3 is independently (C1-C6)alkyl, (C2-C6)alkenyl or (C2-C6)alkynyl;
- and n is a number from zero to 3;
- or a salt thereof,
- or a compound having the following Formula (IB):
- wherein R1 is OH or —NR1aR1b wherein R1a and R1b are independently hydrogen or (C1-C6)alkyl;
- wherein R2 is OH or NR2aR2b, wherein R2a and R2b are independently hydrogen or (C1-C6)alkyl;
- wherein each R3 is independently (C1-C6)alkyl, (C2-C6)alkenyl or (C2-C6)alkynyl;
- and n is a number from zero to 3;
- or a salt thereof;
- and
- at least one additional agent comprising an anionic surfactant, a hydrotrope, a defoaming agent, a solvent, a fluorescent active agent or a combination thereof,
- wherein said composition has a use solution pH below about 4, and wherein the composition has a self-accelerating decomposition temperature (SADT) of at least about 45° C.
16 more elements
Dependencies are inferred from the claim text.