Process for converting carbonaceous material into low tar synthesis gas
AssigneeExpander Energy Inc.
InventorsSteve Kresnyak, Pavel Zahorik
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Abstract
A continuous multi-stage vertically sequenced gasification process for conversion of solid carbonaceous fuel material into clean (low tar) syngas. The process involves forming a pyrolysis residue bed having a uniform depth and width to pass raw syngas there through for an endothermic reaction, while controlling the reduction zone pressure drop, resident time and syngas flow space velocity during the endothermic reaction to form substantially tar free syngas, to reduce carbon content in the pyrolysis residue, and to reduce the temperature of raw syngas as compared to the temperature of the partial oxidation zone.
Claims26
A continuous multi-stage vertically sequenced gasification process for conversion of a solid carbonaceous fuel material into a low tar syngas in a gasifier comprising:
- i) a pyrolysis zone,
- ii) a partial oxidation zone located vertically downstream of the pyrolysis zone, and separated from the pyrolysis zone via a separation member comprising a plurality of upwardly angled vents;
- iii) a reduction zone located vertically downstream of the partial oxidation zone and comprising an angled perforated floor, an openings located centrally relative to the angled perforated floor, and a centrally located deflector;
- the angled perforated floor being sloped downwardly and inwardly toward the opening, wherein the perforated floor is configured, by sizing of perforations therein, to allow passage of a raw syngas therethrough, and to inhibit passage of a raw pyrolysis residue obtainable in the pyrolysis zone, wherein the slope of the angled perforated floor is greater than zero degrees and less than 60 degrees;
- said process comprising the steps of:
- a) feeding the solid carbonaceous fuel material through the upper portion of the pyrolysis zone vertically downwardly towards the lower portion of the pyrolysis zone, while pyrolyzing the solid carbonaceous fuel material into pyrolysis vapours comprising a hydrocarbon material, and the raw pyrolysis residue comprising char and ash;
- b) optionally adding a first oxidant to the lower portion of the pyrolysis zone to achieve a temperature greater than 200° C.;
- c) directing the pyrolysis vapours to the partial oxidation zone, and directing the raw pyrolysis residue downwardly to the reduction zone via the separation member;
- d) adding a second oxidant in the partial oxidation zone to achieve a temperature sufficient to reform the pyrolysis vapours into the raw syngas containing significantly reduced levels of tar;
- e) forming a pyrolysis residue bed having a uniform depth from the raw pyrolysis residue formed in step c) on the floor of the reduction zone;
- f) passing the raw syngas from step d) downwardly through the pyrolysis residue bed formed in step e), and carrying out an endothermic reaction between CO2 and/or H2O in the raw syngas and carbon of the char in the pyrolysis residue bed, while controlling a reduction zone pressure drop, a reduction zone residence time and a reduction zone flow space velocity of the raw syngas during the endothermic reaction to form a substantially tar free enhanced syngas and a decarbonized pyrolysis residue;
- g) passing the substantially tar free enhanced syngas from step f), in upward counter-current flow, to heat the pyrolysis zone and subsequently cool the substantially tar free syngas;
- h) collecting the substantially tar free syngas;
- and
- i) collecting the decarbonized pyrolysis residue from the bottom of the gasifier.
An apparatus for a continuous multi-stage vertically sequenced gasification process for conversion of a solid carbonaceous fuel material into a low tar syngas, the apparatus comprising:
- i) a pyrolysis zone for converting the solid carbonaceous fuel material into pyrolysis vapours comprising a hydrocarbon material, and a carbon rich raw pyrolysis residue comprising char and ash;
- ii) a partial oxidation zone located vertically downstream of the pyrolysis zone for conversion of the hydrocarbon material in the pyrolysis vapours into a raw syngas comprising H2, CO and CO2;
- iii) an endothermic reduction zone located vertically downstream of the partial oxidation zone for converting the raw syngas into a substantially tar free syngas and for reducing the carbon content of the carbon rich raw pyrolysis residue to obtain a decarbonized pyrolysis residue;
- iv) a separation member located between the pyrolysis zone and the partial oxidation zone, the separation member comprising a plurality of upwardly angled vents to allow the pyrolysis vapours into the partial oxidation zone and to inhibit passage of the carbon rich raw pyrolysis residue therethrough, the separation member being configured to direct the carbon rich raw pyrolysis residue into the reduction zone;
- v) an outlet port for the decarbonized pyrolysis residue, located downstream of the reduction zone;
- and
- vi) an outlet for the substantially tar free syngas located downstream of the reduction zone;
- wherein the reduction zone comprises an angled perforated floor, an openings located centrally relative to the angled perforated floor, and a centrally located deflector,
- the angled perforated floor being sloped downwardly and inwardly toward the opening, and configured, by sizing of perforations therein, to allow passage of the raw syngas therethrough and to inhibit passage of the carbon rich raw pyrolysis residue, the opening being in fluidic communication with the outlet port, and configured to allow passage of the decarbonized pyrolysis residue therethrough, wherein the slope of the angled perforated floor is greater than zero degrees and less than 60 degrees.
Dependencies are inferred from the claim text.