Method of producing a multilayered product

A method of producing a multilayered printed indicia or stencil with a process including a crosslinking step, comprising the steps of:

• providing a substrate with a polymeric release film forming a surface thereon;
• providing a coating of a curable composition comprising a polymer powder, at least one plasticizer, and at least one monomer and/or oligomer, onto the polymeric release film surface or a thereon previously applied layer or coating;
• heating the curable coating composition to a first temperature effective to provide a gelled curable coating;
• providing a coating of another curable composition comprising a polymer powder, at least one plasticizer, and at least one monomer and/or oligomer, onto the previously applied layer or coating;
• heating the other curable coating composition to a second temperature, which can be the same as the first, effective to provide a second gelled curable coating;
• before crosslinking is performed, a multilayer-coated substrate is formed by said providing and heating steps is further heated to a third temperature, higher than the first or second temperature, effective to dissolve polymer powder in the gelled curable coatings;
• and
• performing the crosslinking on the heated multilayer-coated substrate, by irradiation and/or subjection to heat at a fourth temperature effective to effect crosslinking,
• wherein, one or both said curable compositions comprise:
• 40-about 68 wt % of the polymer powder,
• 15-about 40 wt % plasticizer,
• about 1-25 wt % monomer and/or oligomer, and
• about 0.5-about 5 wt % initiator.