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US 10,873,034 B2Granted
Condensed cyclic compound and organic light-emitting device including the same
AssigneesSamsung Electronics Co., Ltd., Samsung SDI Co., Ltd.
InventorsSaeyoun Lee, Masaki Numata, Hiroshi Miyazaki, Soonok Jeon, Hosuk Kang, Sooghang Ihn, Miyoung Chae
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Abstract
A condensed cyclic compound represented by Formula 1: Ar1-(L1)a1-Ar2 Formula 1 wherein, in Formula 1, Ar1, Ar2, L1, and a1 are the same as described in the specification.
Claims19
A condensed cyclic compound represented by Formula 1:
- wherein, in Formulae 1, 2-2, 2-4, 3-12, 3-15, and 3-16,
- Ar1 is selected from groups represented by Formulae 2-2 and 2-4;
- Ar2 is selected from groups represented by Formulae 3-12, 3-15, and 3-16;
- L1 is selected from a substituted or unsubstituted C6-C60 arylene group and a substituted or unsubstituted C1-C60 heteroarylene group;
- a1 is selected from 1, 2, and 3;
- X21 is selected from O, S, C(R22)(R23), Si(R22)(R23), Ge(R22)(R23), and P(═O)(R22);
- X31 is selected from O, S, N(R34), C(R34)(R35), Si(R34)(R35), and Ge(R34)(R35);
- provided that when Ar1 is Formula 2-4 and Ar2 is Formula 3-12, when X21 is S, then X31 is selected from O, S, C(R34)(R35), Si(R34)(R35), and Ge(R34)(R35);
- A21 is selected from a C5-C20 carbocyclic group and a C4-C20 heterocyclic group;
- Y21 is selected from a substituted or unsubstituted C6-C60 aryl group and a substituted or unsubstituted C1-C60 heteroaryl group;
- R21 to R23, R31a to R31d, R32a to R32d, R33a to R33d, R34, and R35 are each independently selected from
- hydrogen, deuterium, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a substituted or unsubstituted C1-C60 alkyl group, a substituted or unsubstituted C2-C60 alkenyl group, a substituted or unsubstituted C2-C60 alkynyl group, a substituted or unsubstituted C1-C60 alkoxy group, a substituted or unsubstituted C3-C10 cycloalkyl group, a substituted or unsubstituted C1-C10 heterocycloalkyl group, a substituted or unsubstituted C3-C10 cycloalkenyl group, a substituted or unsubstituted C1-C10 heterocycloalkenyl group, a substituted or unsubstituted C6-C60 aryl group, a substituted or unsubstituted C6-C60 aryloxy group, a substituted or unsubstituted C6-C60 arylthio group, a substituted or unsubstituted C1-C60 heteroaryl group, a substituted or unsubstituted monovalent non-aromatic condensed polycyclic group, and a substituted or unsubstituted monovalent non-aromatic condensed heteropolycyclic group;
- b21 is selected from 1, 2, 3, 4, 5, 6, 7, and 8;
- and
- * denotes a binding site to a neighboring atom.
12 more elements
An organic light-emitting device comprising:
- a first electrode;
- a second electrode;
- and
- an organic layer disposed between the first electrode and the second electrode,
- wherein the organic layer comprises an emission layer and at least one condensed cyclic compound represented by Formula 1,
- wherein the emission layer emits blue light:
- wherein, in Formulae 1, 2-1 to 2-4, 3-1, and 3-2,
- Ar1 is selected from groups represented by Formulae 2-1 to 2-4;
- Ar2 is selected from groups represented by Formulae 3-1 and 3-2;
- L1 is selected from a substituted or unsubstituted C6-C60 arylene group and a substituted or unsubstituted C1-C60 heteroarylene group;
- a1 is selected from 1, 2, and 3;
- X21 is selected from O, S, C(R22)(R23), Si(R22)(R23), Ge(R22)(R23), and P(═O)(R22);
- X31 is selected from O, S, N(R34), C(R34)(R35), Si(R34)(R35), and Ge(R34)(R35);
- A21, A31, and A33 are each independently selected from a C5-C20 carbocyclic group and a C4-C20 heterocyclic group;
- A32 is selected from a C5-C20 carbocyclic group;
- Y21 is selected from a substituted or unsubstituted C6-C60 aryl group and a substituted or unsubstituted C1-C60 heteroaryl group;
- R21 to R23 and R31 to R35 are each independently selected from hydrogen, deuterium, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a substituted or unsubstituted C1-C60 alkyl group, a substituted or unsubstituted C2-C60 alkenyl group, a substituted or unsubstituted C2-C60 alkynyl group, a substituted or unsubstituted C1-C60 alkoxy group, a substituted or unsubstituted C3-C10 cycloalkyl group, a substituted or unsubstituted C1-C10 heterocycloalkyl group, a substituted or unsubstituted C3-C10 cycloalkenyl group, a substituted or unsubstituted C1-C10 heterocycloalkenyl group, a substituted or unsubstituted C6-C60 aryl group, a substituted or unsubstituted C6-C60 aryloxy group, a substituted or unsubstituted C6-C60 arylthio group, a substituted or unsubstituted C1-C60 heteroaryl group, a substituted or unsubstituted monovalent non-aromatic condensed polycyclic group, and a substituted or unsubstituted monovalent non-aromatic condensed heteropolycyclic group;
- b21 is selected from 1, 2, 3, 4, 5, 6, 7, and 8;
- b31 to b33 are each independently selected from 1, 2, 3, 4, 5, and 6;
- and
- * denotes a binding site to a neighboring atom,
- wherein the emission layer comprises the condensed cyclic compound, wherein the emission layer further comprises a host, and wherein the condensed cyclic compound is a dopant.
19 more elements
Dependencies are inferred from the claim text.