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US 10,864,503 B2Granted
Process for the preparation of a hydrocracking catalyst
AssigneeShell Oil Company
InventorsHermanus Jongkind, Wiebe Sjoerd Kijlstra, Bart Pelgrim, Marcello Stefano Rigutto, Ferry Winter
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Abstract
This invention relates to a process for the preparation of a hydrocracking catalyst and its use. A zeolite Y having specifically defined properties is mixed with an alumina binder component and a first metals-containing solution that is extruded to form an extruded mixture. The extruded mixture is dried and calcined. The dried and calcined mixture is then impregnated with a second metals-containing solution.
Claims12
A process for the preparation of a hydrocracking catalyst, which comprises the steps of:
- (a) mixing a zeolite Y, having a unit cell size in the range of from 24.42 to 24.52 Å, a bulk silica to alumina molar ratio (SAR) in the range of from 10 to 15, and a surface area of from 910 to 1020 m2/g, with an alumina binder component, a first Group VIB metal component, and a first Group VIII metal component, which at least one of the metal components is contained in at least one first metal-containing acidic aqueous solution, to thereby provide a mixture, wherein the zeolite Y is present in the mixture in an amount of 40 wt. % or greater, based on the total weight of the zeolite Y and the alumina binder component;
- (b) extruding the mixture to provide an extruded mixture;
- (c) drying the extruded mixture to provide a dried and extruded mixture;
- (d) calcining the dried and extruded mixture to provide a calcined product;
- (e) impregnating the calcined product with a second Group VIB metal component and a second Group VIII metal component, which at least one of the metal components is contained in at least one second metal-containing solution to provide an impregnated product;
- and
- (f) calcining the impregnated product at a temperature in the range of from 350° C. to 850° C.
4 more elements
Dependencies are inferred from the claim text.