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US 10,766,972 B2Granted
Modified conjugated diene-based polymer and method for producing the same, and modified conjugated diene-based polymer composition
AssigneeAsahi Kasei Kabushiki Kaisha
InventorsChigusa Yamada, Yukio Yamaura, Kenta Hisamura, Junichi Yoshida
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Abstract
The present invention provides a modified conjugated diene-based polymer, wherein the Mooney stress-relaxation rate measured at 110° C. is 0.45 or less, and the modification percentage is 75% by mass or more.
Claims19
A modified conjugated diene-based polymer comprising a nitrogen atom,
- wherein a content of the nitrogen atom is 40 ppm by mass or more based on a total amount of the modified conjugated diene-based polymer,
- a Mooney stress-relaxation rate measured at 110° C. is 0.45 or less,
- a modification percentage is 84.8% by mass or more, and
- a ratio of a first weight-average molecular weight to a first number-average molecular weight is 1.50 or more and 3.50 or less.
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A method for producing a modified conjugated diene-based polymer comprising a nitrogen atom, the method comprising steps of:
- polymerizing at least a conjugated diene compound in a presence of an organolithium compound having at least one nitrogen atom in a molecule to obtain a conjugated diene-based polymer;
- and
- modifying the conjugated diene-based polymer with a modifier having four or more alkoxy groups bonding to a silyl group and a tertiary amino group in one molecule,
- wherein, in the modification step, a content of the conjugated diene compound is 100 ppm by mass or more and 50000 ppm by mass or less based on a total amount of a monomer and a polymer,
- wherein the modified conjugated diene-based polymer comprising a nitrogen atom has a content of the nitrogen atom of 25 ppm by mass or more based on a total amount of the modified conjugated diene-based polymer,
- a Mooney stress-relaxation rate measured at 110° C. of 0.45 or less,
- a modification percentage of 75% by mass or more, and
- a ratio of a first weight-average molecular weight to a first number-average molecular weight of 1.50 or more and 3.50 or less.
5 more elements
Dependencies are inferred from the claim text.