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US 10,766,022 B2Granted
Hydrocarbon conversion catalyst composition
AssigneeShell Oil Company
InventorsLászló Domokos, Laurent Georges Huve, Hermanus Jongkind, Aan Hendrik Klazinga, Marcello Stefano Rigutto
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Abstract
A hydrocarbon conversion catalyst composition which comprises dealuminated ZSM-48 and/or EU-2 zeolite and a refractory oxide binder essentially free of alumina, processes for preparing such composition and processes for converting hydrocarbon feedstock with the help of such compositions.
Claims14
A catalytic dewaxing process for reducing the pour point of a wax-containing feedstock, said catalytic dewaxing process comprises:
- contacting under dewaxing conditions said wax-containing feedstock, having a 10% distillation point at 200° C. as measured by ASTM D-2887-93, with a dewaxing catalyst composition, wherein said dewaxing conditions include a contacting temperature in the range of from 250 to 400° C., a contacting pressure in the range of from 5×105 to 200×105 Pa, and a liquid hourly space velocity in the range of from 0.1 to 10 hr −1, and thereby providing a reduction of the pour point of said wax-containing feedstock by at least 10° C.;
- wherein said dewaxing catalyst comprises a dealuminated dried and calcined extrudate, wherein said extrudate, before drying and calcination, comprises a binder that is essentially free of alumina and which comprises both a silica powder, wherein said silica powder comprises powder particles having a mean diameter between 10 μm and 200 μm, and a silica sol;
- EU-2 zeolite, wherein said EU-2 zeolite has a silica-to-alumina molar bulk ratio before the dealumination of said dried and calcined extrudate in the range of from 100 to 210;
- a plasticising agent;
- and water in an amount of at least 35% and not exceeding 60% by weight of the extrudate before drying and calcination;
- and
- a catalytic metal selected from the group consisting of platinum, palladium and nickel;
- wherein the dealumination of said dried and calcined extrudate is done by contacting said dried and calcined extrudate with an aqueous solution of fluorosilicate salt having a concentration of at least 0.005 mole of fluorosilicate salt/liter and at most 0.5 mole of fluorosilicate salt/liter and at a temperature in the range of from 10° C. to 120° C., and
- wherein the amount of said EU-2 zeolite present in said catalyst composition is at least 15% wt. of said catalyst composition;
- and
- wherein the EU-2 zeolite is in the form of EU-2 zeolite particles, where the average aluminum concentration of the EU-2 zeolite particles is at least two times the aluminum concentration at the surface of the particles.
8 more elements
Dependencies are inferred from the claim text.