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US 10,501,691 B2Granted
Piperidine derivatives and liquid-crystalline medium
AssigneeMerck Patent GmbH
InventorsAchim Goetz, Rocco Fortte, Martin Engel, Sabrina Maag, Thorsten Kodek
Life of this patent
Estimating the term…
Abstract
Disclosed are compounds of the formula I, liquid-crystalline media comprising the compounds of formula I, and the use of these liquid-crystalline media in liquid-crystal displays.
Claims19
A compound of formula I
- where
- Sp1 and Sp2 are each independently a flexible linking or bridging group, which does not contain a —CO—group,
- A and B are each independently:
- a) trans-1,4-cyclohexylene, 1,4-cyclohexenylene or 1,4′-bicyclohexylene, in which one or two nonadjacent CH2 groups are optionally replaced by —O—and/or —S—and in which one or more hydrogen atoms are optionally replaced by F, or
- b) 1,4-phenylene or 1,3-phenylene, in which one or two nonadjacent CH groups are optionally replaced by N and in which one or more hydrogen atoms are optionally replaced by L, or
- c)
- in which one or more hydrogen atoms are optionally replaced by L, and/or one or more double bonds are optionally replaced by single bonds, and/or one or more CH groups are optionally replaced by N,
- i and j are each independently 0 or 1,
- Z0 is a single bond, —CH2—, —CF2—, —CO—, —O—, —NH—, —NH—(CO)—, —CH2CH2—, —CH═CH—, —CF2O—, —OCF2—, —CH2O—, —OCH2—, —COO—, —OCO—, —C2F4—or —CF═CF—,
- and
- L is the same or different at each instance and is F, Cl, CN or a straight-chain or branched, in each case optionally fluorinated alkyl, alkoxy, arylalkyl or alkylarylalkyl having 1 to 15 carbon atoms, in which one or more nonadjacent CH2 groups are optionally replaced by —O—and/or —S—,
- with the proviso that the following compound is not included
9 more elements
A compound of formula I
- where
- Sp1 and Sp2 are each independently alkylene having 1 to 12 carbon atoms which is optionally mono or polysubstituted by F, Cl or CN, and in which one or more nonadjacent CH2 groups are optionally each independently replaced by —O—, —S—, —NH, —COO—, —OCO—, —OCO—O—, —CH═CH—or —C≡C—,
- A and B are each independently:
- a) trans-1,4-cyclohexylene, 1,4-cyclohexenylene or 1,4′-bicyclohexylene, in which one or two nonadjacent CH2 groups are optionally replaced by —O—and/or —S—and in which one or more hydrogen atoms are optionally replaced by F, or
- b) 1,4-phenylene or 1,3-phenylene, in which one or two nonadjacent CH groups are optionally replaced by N and in which one or more hydrogen atoms are optionally replaced by L, or
- c)
- in which one or more hydrogen atoms are optionally replaced by L, and/or one or more double bonds are optionally replaced by single bonds, and/or one or more CH groups are optionally replaced by N,
- i and j are each independently 0 or 1,
- Z0 is a single bond, —CH2—, —CF2—, —CO—, —O—, —NH—, —NH—(CO)—, —CH2CH2—, —CH═CH—, —CF2O—, —OCF2—, —CH2O—, —OCH2—, —COO—, —OCO—, —C2F4—or —CF═CF—,
- and
- L is the same or different at each instance and is F, Cl, CN or a straight-chain or branched, in each case optionally fluorinated alkyl, alkoxy, arylalkyl or alkylarylalkyl having 1 to 15 carbon atoms, in which one or more nonadjacent CH2 groups are optionally replaced by —O—and/or —S—,
- with the proviso that the following compound is not included
9 more elements
Dependencies are inferred from the claim text.