Poly(amic acid) synthesis and conversion to high molecular weight polyimide
AssigneeSabic Global Technologies B.V.
InventorViswanathan Kalyanaraman
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Abstract
A process is disclosed for synthesis of a poly(amic acid), including reacting a dianhydride and a diamine in the presence of a tertiary amine, tertiary ammonium salt, tertiary ammonium hydroxide, secondary amine, secondary ammonium salt, secondary ammonium hydroxide, quaternary ammonium salt, quaternary ammonium hydroxide, ammonium hydroxide, or a combination comprising at least one of the foregoing, in water, at a temperature of 60 C to 180 C, or 60 C to 100 C, or 100 C to 180 C, under an inert atmosphere, with agitation, to produce an aqueous poly(amic acid).
Claims18
A process for synthesis of a poly(amic acid), the process comprising:
- reacting a dianhydride and a diamine in the presence of a higher monoamine comprising tertiary amine, tertiary ammonium salt, tertiary ammonium hydroxide, secondary amine, secondary ammonium salt, secondary ammonium hydroxide, quaternary ammonium salt, quaternary ammonium hydroxide, ammonium hydroxide, or a combination comprising at least one of the foregoing, in a reaction medium comprising at least 95 volume percent water, at a temperature of 80° C. to 180° C., under an inert atmosphere, with agitation, to produce an aqueous poly(amic acid).
Dependencies are inferred from the claim text.