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US 10,501,341 B2Granted
Method for removing heavy metals from wastewater
AssigneeKing Fahd University of Petroleum and Minerals
InventorsOthman Charles Sadeq Al Hamouz, Oluwafemi S. Akintola, Tawfik Abdo Saleh Awadh
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Abstract
Cross-linked polymeric resins from anilines linked together with polyamine alkyl chains. A process for producing the cross-linked polymeric resins by Mannich-type polycondensation of anilines and diaminoalkanes linked together by an aldehyde and subsequent basification. In addition, a method for removing heavy metals, such as Pb (II) and As (V) from aqueous solution via contacting and treatment with the cross-linked polymeric resins.
Claims12
A method for removing a heavy metal from an aqueous solution, comprising:
- contacting a cross-linked polymeric resin with the aqueous solution comprising at least one heavy metal;
- wherein the cross-linked polymeric resin has the following formula (I)
- or a salt, solvate, tautomer or stereoisomer derived from the cross-linked polymeric resin of formula (I);
- wherein each R1 is independently selected from H, an alkyl, a cycloalkyl, and an aryl;
- each R2 is independently selected from H, —F, —Cl, —Br, —CN, —OR3, an alkyl, a cycloalkyl, and an aryl;
- each R3 is independently selected from —H, an alkyl, a cycloalkyl, and an aryl;
- n is a positive whole number in the range of 2-16;
- X is a positive whole number;
- and
- A1 forms a bond to A2 of another monomer unit;
- and
- adsorbing the heavy metal onto the cross-linked polymeric resin to form a heavy metal loaded cross-linked polymeric resin and a heavy metal depleted aqueous solution.
9 more elements
Dependencies are inferred from the claim text.