Methods of forming si3nX, methods of forming insulator material between a control gate and charge-storage material of a programmable charge-storage transistor, and methods of forming an array of elevationally-extending strings of memory cells and a programmable charge-storage transistor manufactured in accordance with methods

A method of forming Si3Nx, where “x” is less than 4 and at least 3, comprising:

• decomposing silicon tetrachloride into at least two decomposition species that are different from one another, at least one of the at least two different decomposition species comprising Si;
• after the decomposing the Si-precursor molecule, contacting an outer substrate surface with the at least two decomposition species, at least one of the decomposition species that comprises Si attaching to the outer substrate surface to comprise an attached species;
• and
• after the contacting the outer substrate surface, contacting the attached species with a N-comprising precursor that reacts with the attached species to form a reaction product comprising Si3Nx, where “x” is less than 4 and at least 3.

A method of forming Si3Nx, where “x” is less than 4 and at least 3, comprising:

• providing a single Si-comprising precursor into a chamber;
• decomposing the single Si-comprising precursor into at least two decomposition species that are different from one another, wherein each of at least two of said different decomposition species comprises Si;
• after the decomposing the Si-precursor molecule, contacting an outer substrate surface with the at least two decomposition species, at least one of the decomposition species that comprises Si attaching to the outer substrate surface to comprise an attached species;
• and
• after the contacting the outer substrate surface, contacting the attached species with a N-comprising precursor that reacts with the attached species to form a reaction product comprising Si3Nx, where “x” is less than 4 and at least 3.

A method of forming Si3Nx, where “x” is less than 4 and at least 3, comprising:

• providing a single silicon- and chlorine-comprising precursor into a chamber, the single silicon- and chlorine-comprising precursor being selected from silicon tetrachloride, hexachlorodisilane and trichlorosilane;
• decomposing the silicon- and chlorine-comprising precursor molecule into at least two decomposition species that are different from one another, at least one of the at least two different decomposition species comprising Si, the decomposing comprising thermal decomposition of the silicon- and chlorine-comprising precursor molecule directly above an outer substrate surface at a temperature of at least 500° C.;
• contacting the outer substrate surface with the at least two decomposition species, at least one of the decomposition species that comprises Si attaching to the outer substrate surface to comprise an attached species and attaching the at least one of the decomposition species that comprises Si to the attached species;
• and
• after contacting the outer substrate surface with the at least two decomposition species, contacting the attached species with ammonia that reacts with the attached species to form a reaction product comprising Si3Nx, where “x” no more than 3.90 and at least 3.

A method of forming insulator material that is ultimately between a control gate and charge-storage material of a programmable charge-storage transistor, comprising:

• decomposing a Si-comprising precursor molecule into at least two decomposition species that are different from one another, at least one of the at least two different decomposition species comprising Si;
• contacting an outer substrate surface with the at least two decomposition species, at least one of the decomposition species that comprises Si attaching to the outer substrate surface to comprise an attached species;
• contacting the attached species with a N-comprising precursor that reacts with the attached species to form a reaction product comprising Si3Nx, where “x” is less than 4 and at least 3;
• and
• providing the reaction product between a control gate and charge-storage material of a programmable charge-storage transistor.

A method of forming an array of elevationally-extending strings of memory cells, the method comprising:

• forming a stack comprising vertically-alternating insulative tiers and wordline tiers, the wordline tiers comprising control-gate material, channel openings extending into the alternating tiers;
• forming charge-blocking material comprising Si3Nx, where “x” is less than 4 and at least 3, in the channel openings elevationally along the control-gate material, the forming of the Si3Nx comprising:
• decomposing a Si-comprising precursor molecule into at least two decomposition species that are different from one another, at least one of the at least two different decomposition species comprising Si;
• contacting an outer substrate surface with the at least two decomposition species, at least one of the decomposition species that comprises Si attaching to the outer substrate surface to comprise an attached species;
• and
• after the contacting the outer substrate surface with the at least two decomposition species, contacting the attached species with a N-comprising precursor that reacts with the attached species to form a reaction product comprising Si3Nx, where “x” is less than 4 and at least 3;
• forming charge-storage material in the channel openings elevationally along the charge-blocking material comprising Si3Nx;
• and
• forming insulative charge-passage material then transistor channel material in the channel openings laterally over the charge-storage material;
• providing the control-gate material to have terminal ends corresponding to control-gate regions of individual memory cells, with the charge-blocking material being between the charge-storage material and individual of the control-gate regions.

A method of forming an array of elevationally-extending strings of memory cells, the method comprising:

• forming a stack comprising vertically-alternating insulative tiers and wordline tiers, the wordline tiers comprising control-gate material having terminal ends corresponding to control-gate regions of individual memory cells, channel openings extending into the alternating tiers, the control-gate material being laterally-recessed from laterally-innermost surfaces of the channel openings;
• forming charge-blocking material comprising Si3Nx, where “x” is less than 4 and at least 3, in the channel openings elevationally along the laterally-recessed control-gate material, the forming of the Si3Nx comprising:
• decomposing a Si-comprising precursor molecule into at least two decomposition species that are different from one another, at least one of the at least two different decomposition species comprising Si;
• contacting an outer substrate surface with the at least two decomposition species, at least one of the decomposition species that comprises Si attaching to the outer substrate surface to comprise an attached species;
• and
• after the contacting an outer substrate surface with the at least two decomposition species, contacting the attached species with a N-comprising precursor that reacts with the attached species to form a reaction product comprising Si3Nx, where “x” is less than 4 and at least 3;
• forming charge-storage material in the channel openings elevationally along the charge-blocking material comprising Si3Nx;
• and
• forming insulative charge-passage material then transistor channel material in the channel openings laterally over the charge-storage material.

A method of forming an array of elevationally-extending strings of memory cells, the method comprising:

• forming a stack comprising vertically-alternating tiers of different composition first and second materials, the first material being insulative;
• forming elevationally-extending channel openings into the alternating tiers;
• forming charge-blocking material comprising Si3Nx, where “x” is less than 4 and at least 3, in the channel openings elevationally along the alternating tiers, the forming of the Si3Nx comprising:
• decomposing a Si-comprising precursor molecule into at least two decomposition species that are different from one another, at least one of the at least two different decomposition species comprising Si;
• contacting an outer substrate surface with the at least two decomposition species, at least one of the decomposition species that comprises Si attaching to the outer substrate surface to comprise an attached species;
• and
• after the contacting an outer substrate surface with the at least two decomposition species, contacting the attached species with a N-comprising precursor that reacts with the attached species to form a reaction product comprising Si3Nx, where “x” is less than 4 and at least 3;
• forming charge-storage material in the channel openings elevationally along the alternating tiers and the charge-blocking material comprising Si3Nx;
• forming insulative charge-passage material in the channel openings elevationally along the charge-storage material;
• forming transistor channel material in the channel openings elevationally along the insulative charge-passage material;
• and
• after forming the transistor channel material, replacing at least some of the second material with control-gate material having terminal ends corresponding to control-gate regions of individual memory cells.

A programmable charge-storage transistor comprising:

• channel material;
• insulative charge-passage material;
• charge-storage material;
• a control gate;
• and
• charge-blocking insulator material between the charge-storage material and the control gate, the charge-blocking insulator material comprising Si3Nx, where “x” is less than 4 and at least 3.