Electrophotographic photosensitive member, process cartridge, and image forming apparatus
AssigneeKYOCERA Document Solutions Inc.
InventorsTomofumi Shimizu, Kiichiro Oji
Life of this patent
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Abstract
An electrophotographic photosensitive member includes a conductive substrate and a photosensitive layer. The photosensitive layer is a single-layer photosensitive layer and contains a charge generating material, a hole transport material, an electron transport material, and a binder resin. The binder resin has a viscosity average molecular weight of at least 25,000 and no greater than 50,000. A strain at break of the photosensitive layer is at least 4.9% and no greater than 13.0%. A scratch resistant depth of the photosensitive layer is no greater than 0.50 μm.
Claims11
An electrophotographic photosensitive member comprising a conductive substrate and a photosensitive layer, wherein
- the photosensitive layer is a single-layer photosensitive layer and contains a charge generating material, a hole transport material, an electron transport material, and a binder resin,
- the binder resin has a viscosity average molecular weight of at least 25,000 and no greater than 50,000,
- a strain at break of the photosensitive layer is at least 4.9% and no greater than 13.0%, the strain at break being a value determined from a stress-strain curve obtained by pulling the photosensitive layer using a tensile tester at a rate of 5 mm/minute,
- a scratch resistant depth of the photosensitive layer is no greater than 0.50 μm, the scratch resistant depth being a value measured through first to fourth steps described below using a scratching apparatus in accordance with JIS K5600-5-5,
- the scratching apparatus includes a fixture and a scratching stylus,
- the scratching stylus has a semispherical sapphire tip having a diameter of 1 mm,
- in the first step, the photosensitive member is fixed to an upper surface of the fixture with a longitudinal direction of the photosensitive member in parallel with a longitudinal direction of the fixture,
- in the second step, the scratching stylus is brought into vertical contact with a surface of the photosensitive layer,
- in the third step, the fixture and the photosensitive member fixed to the upper surface of the fixture are caused to move by 30 mm at a rate of 30 mm/minute in the longitudinal direction of the fixture while a load of 10 g is applied from the scratching stylus to the photosensitive layer,
- in the fourth step, the greatest depth of a scratch created on the surface of the photosensitive layer through the third step is measured as the scratch resistant depth, and
- the binder resin includes a polyarylate resin represented by general formula (1) shown below
- where in general formula (1),
- r, s, t, and u each represent, independently of one another, a number greater than or equal to 0
- r+s+t+u=100,
- r+t=s+u,
- r/(r+t) is at least 0.00 and no greater than 0.90,
- s/(s+u) is at least 0.00 and no greater than 0.90,
- X is a divalent group represented by chemical formula (1A) or (1B) shown below, and
- Y is a divalent group represented by chemical formula (2A) or (2B) shown below
Dependencies are inferred from the claim text.